Spectral, electrochemical, and catalytic properties of a homologous series of manganese porphyrins as cytochrome P450 model: The effect of the degree of β-bromination

A homologous series of β-brominated porphyrins derived from meso-tetrakis(4-carbomethoxyphenyl)porphyrinatomanganese(III) chloride, i.e., Mn(III)(Br x TCMPP)Cl ( x = 0, 2, 4, 6, and 8), was prepared and investigated as cytochrome P450 models. Hydroxylations of cyclohexane by iodosylbenzene (PhIO) an...

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Veröffentlicht in:	Journal of inorganic biochemistry 2008-10, Vol.102 (10), p.1932-1941
Hauptverfasser:	Silva, Dayse Carvalho da, DeFreitas-Silva, Gilson, Nascimento, Eliane do, Rebouças, Júlio Santos, Barbeira, Paulo Jorge Sanches, Carvalho, Maria Eliza Moreira Dai de, Idemori, Ynara Marina
Format:	Artikel
Sprache:	eng
Schlagworte:	Catalysis Cyclohexane hydroxylation Cyclohexanes - metabolism Cytochrome P-450 Enzyme System - chemistry Electrochemistry Halogenation Iodobenzene diacetate Iodosylbenzene Manganese - chemistry Manganese - metabolism Manganese porphyrins Metalloporphyrins - chemical synthesis Metalloporphyrins - chemistry Oxidation-Reduction β-Halogenated porphyrins
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