Structures of two haptotropic isomers generated by the sliding of 1,3,5-triene ligands on a Pd-Pd-Pd chain

Structures of two haptotropic isomers generated by the sliding of 1,3,5-triene ligands on a Pd-Pd-Pd chain

Two haptotropic isomers of [Pd3(micro3-DMVC)2(CH3CN)2][BF4]2 (DMVC=1,2-di-(E)-carbomethoxyvinylcyclopentene) were structurally determined by X-ray crystallographic analyses; a monoclinic crystal contained a symmetric sandwich complex (micro3-eta2:eta2:eta2-coordination of DMVC ligands) and a triclin...

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2008-09 (34), p.4061-4063
Hauptverfasser: Murahashi, Tetsuro, Mino, Yukari, Chiyoda, Koji, Ogoshi, Sensuke, Kurosawa, Hideo
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creator Murahashi, Tetsuro
Mino, Yukari
Chiyoda, Koji
Ogoshi, Sensuke
Kurosawa, Hideo
description Two haptotropic isomers of [Pd3(micro3-DMVC)2(CH3CN)2][BF4]2 (DMVC=1,2-di-(E)-carbomethoxyvinylcyclopentene) were structurally determined by X-ray crystallographic analyses; a monoclinic crystal contained a symmetric sandwich complex (micro3-eta2:eta2:eta2-coordination of DMVC ligands) and a triclinic crystal contained an unsymmetric sandwich complex (micro3-eta2:eta3:eta1-coordination of DMVC ligands), where the latter are connected to each other by C-HO hydrogen bonds.
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title Structures of two haptotropic isomers generated by the sliding of 1,3,5-triene ligands on a Pd-Pd-Pd chain
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