Calibration method at the N K-edge using interstitial nitrogen gas in solid-state nitrogen-containing inorganic compounds
The standard method of soft X‐ray beamline calibration at the N K‐edge uses the ν = 0 peak transition of gas‐phase N2. Interstitial N2 gas trapped or formed within widely available solid‐state ammonium‐ and amine‐containing salts can be used for this purpose, bypassing gas‐phase measurements. Eviden...
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| Veröffentlicht in: | Journal of synchrotron radiation 2008-09, Vol.15 (5), p.532-534 |
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| container_title | Journal of synchrotron radiation |
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| creator | Gillespie, Adam W. Walley, Fran L. Farrell, Richard E. Regier, Tom Z. Blyth, Robert I. R. |
| description | The standard method of soft X‐ray beamline calibration at the N K‐edge uses the ν = 0 peak transition of gas‐phase N2. Interstitial N2 gas trapped or formed within widely available solid‐state ammonium‐ and amine‐containing salts can be used for this purpose, bypassing gas‐phase measurements. Evidence from non‐nitrogen‐containing compounds (KH2PO4) and from He‐purged ammonium salts suggest that production of N2 gas is through beam‐induced decomposition. Compounds with nitrate or nitrite as anions produce coincident features and are not suitable for this calibration method. |
| doi_str_mv | 10.1107/S0909049508014283 |
| format | Article |
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Compounds with nitrate or nitrite as anions produce coincident features and are not suitable for this calibration method.</description><identifier>ISSN: 1600-5775</identifier><identifier>ISSN: 0909-0495</identifier><identifier>EISSN: 1600-5775</identifier><identifier>DOI: 10.1107/S0909049508014283</identifier><identifier>PMID: 18728328</identifier><language>eng</language><publisher>5 Abbey Square, Chester, Cheshire CH1 2HU, England: International Union of Crystallography</publisher><subject>ammonium ; calibration ; chloride ; hydroxylamine ; K-edge ; NEXAFS ; nitrate ; nitrite ; nitrogen ; phosphate ; sulfate ; XANES</subject><ispartof>Journal of synchrotron radiation, 2008-09, Vol.15 (5), p.532-534</ispartof><rights>International Union of Crystallography, 2008</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c3322-cb21ab1e57d8eb09b8ed70e86f4400823dc66f0fb1b66621b24618bd4b9fda853</citedby></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://onlinelibrary.wiley.com/doi/pdf/10.1107%2FS0909049508014283$$EPDF$$P50$$Gwiley$$H</linktopdf><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1107%2FS0909049508014283$$EHTML$$P50$$Gwiley$$H</linktohtml><link.rule.ids>314,780,784,1416,11561,27923,27924,45573,45574,46051,46475</link.rule.ids><linktorsrc>$$Uhttps://onlinelibrary.wiley.com/doi/abs/10.1107%2FS0909049508014283$$EView_record_in_Wiley-Blackwell$$FView_record_in_$$GWiley-Blackwell</linktorsrc><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/18728328$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Gillespie, Adam W.</creatorcontrib><creatorcontrib>Walley, Fran L.</creatorcontrib><creatorcontrib>Farrell, Richard E.</creatorcontrib><creatorcontrib>Regier, Tom Z.</creatorcontrib><creatorcontrib>Blyth, Robert I. R.</creatorcontrib><title>Calibration method at the N K-edge using interstitial nitrogen gas in solid-state nitrogen-containing inorganic compounds</title><title>Journal of synchrotron radiation</title><addtitle>J. Synchrotron Rad</addtitle><description>The standard method of soft X‐ray beamline calibration at the N K‐edge uses the ν = 0 peak transition of gas‐phase N2. Interstitial N2 gas trapped or formed within widely available solid‐state ammonium‐ and amine‐containing salts can be used for this purpose, bypassing gas‐phase measurements. Evidence from non‐nitrogen‐containing compounds (KH2PO4) and from He‐purged ammonium salts suggest that production of N2 gas is through beam‐induced decomposition. Compounds with nitrate or nitrite as anions produce coincident features and are not suitable for this calibration method.</description><subject>ammonium</subject><subject>calibration</subject><subject>chloride</subject><subject>hydroxylamine</subject><subject>K-edge</subject><subject>NEXAFS</subject><subject>nitrate</subject><subject>nitrite</subject><subject>nitrogen</subject><subject>phosphate</subject><subject>sulfate</subject><subject>XANES</subject><issn>1600-5775</issn><issn>0909-0495</issn><issn>1600-5775</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2008</creationdate><recordtype>article</recordtype><recordid>eNqFkcFu1DAURS0Eou3AB7BBXrEL2HFiO0s0goEySoVahFhZdvySGhJ7ajuC-XuCMipILCovnqV3zl28i9ALSl5TSsSba9Isr2pqIgmtSskeoXPKCSlqIerH__zP0EVK3wmhXJTsKTqjUix0Kc_RcatHZ6LOLng8Qb4NFuuM8y3gFn8qwA6A5-T8gJ3PEFN22ekRe5djGMDjQadlg1MYnS1S1hnud0UXfNbOr3KIg_auw12YDmH2Nj1DT3o9Jnh-mhv05f27m-2HYn-1-7h9uy86xsqy6ExJtaFQCyvBkMZIsIKA5H1VESJLZjvOe9IbajjnJTVlxak0tjJNb7Ws2Qa9WnMPMdzNkLKaXOpgHLWHMCfFm0owRtmDIKuWm3NOF5CuYBdDShF6dYhu0vGoKFF_ilH_FbM4L0_hs5nA_jVOTSyAXIGfboTjw4nq8vrb1U1dLxfYoGJVXcrw617V8YfigolafW13atfKXfW5bdWe_QaPt6mx</recordid><startdate>200809</startdate><enddate>200809</enddate><creator>Gillespie, Adam W.</creator><creator>Walley, Fran L.</creator><creator>Farrell, Richard E.</creator><creator>Regier, Tom Z.</creator><creator>Blyth, Robert I. 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Synchrotron Rad</addtitle><date>2008-09</date><risdate>2008</risdate><volume>15</volume><issue>5</issue><spage>532</spage><epage>534</epage><pages>532-534</pages><issn>1600-5775</issn><issn>0909-0495</issn><eissn>1600-5775</eissn><abstract>The standard method of soft X‐ray beamline calibration at the N K‐edge uses the ν = 0 peak transition of gas‐phase N2. Interstitial N2 gas trapped or formed within widely available solid‐state ammonium‐ and amine‐containing salts can be used for this purpose, bypassing gas‐phase measurements. Evidence from non‐nitrogen‐containing compounds (KH2PO4) and from He‐purged ammonium salts suggest that production of N2 gas is through beam‐induced decomposition. Compounds with nitrate or nitrite as anions produce coincident features and are not suitable for this calibration method.</abstract><cop>5 Abbey Square, Chester, Cheshire CH1 2HU, England</cop><pub>International Union of Crystallography</pub><pmid>18728328</pmid><doi>10.1107/S0909049508014283</doi><tpages>3</tpages></addata></record> |
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| ispartof | Journal of synchrotron radiation, 2008-09, Vol.15 (5), p.532-534 |
| issn | 1600-5775 0909-0495 1600-5775 |
| language | eng |
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| source | Wiley-Blackwell Open Access Titles |
| subjects | ammonium calibration chloride hydroxylamine K-edge NEXAFS nitrate nitrite nitrogen phosphate sulfate XANES |
| title | Calibration method at the N K-edge using interstitial nitrogen gas in solid-state nitrogen-containing inorganic compounds |
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