3D Network of Four-Bonded Germanium: A Link between Open and Dense

Under pressure: The new modification Ge(hR8) is obtained upon pressurization of clathrate‐type Ge(cF136) or controlled decompression of a Ge(tI4)‐type high‐pressure phase. The atomic arrangement comprises four‐bonded germanium atoms with a topological organization bearing remarkable similarity to hi...

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Veröffentlicht in:	Angewandte Chemie (International ed.) 2008-08, Vol.47 (36), p.6790-6793
Hauptverfasser:	Schwarz, Ulrich, Wosylus, Aron, Böhme, Bodo, Baitinger, Michael, Hanfland, Michael, Grin, Yuri
Format:	Artikel
Sprache:	eng
Schlagworte:	allotropy chemical bonding germanium modification host-guest systems
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description	Under pressure: The new modification Ge(hR8) is obtained upon pressurization of clathrate‐type Ge(cF136) or controlled decompression of a Ge(tI4)‐type high‐pressure phase. The atomic arrangement comprises four‐bonded germanium atoms with a topological organization bearing remarkable similarity to high‐pressure host–guest assemblies of other main‐group elements.
doi_str_mv	10.1002/anie.200800914
format	Article
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subjects	allotropy chemical bonding germanium modification host-guest systems
title	3D Network of Four-Bonded Germanium: A Link between Open and Dense
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