Direct generation of hydrogen peroxide from formic acid and O2 using heterogeneous Pd/gamma-Al2O3 catalysts

Direct generation of hydrogen peroxide from formic acid and O2 using heterogeneous Pd/gamma-Al2O3 catalysts

Hydrogen peroxide formation is achieved with remarkable productivity at ambient conditions (25 degrees C and atmospheric pressure) in aqueous medium using a heterogeneous catalytic system; formic acid is decomposed in the presence of a continuous flow of O(2) over Pd/gamma-Al(2)O(3) catalyst leading...

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2008-09 (33), p.3885-3887
Hauptverfasser: Yalfani, Mohammad S, Contreras, Sandra, Medina, Francesc, Sueiras, Jesus
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creator Yalfani, Mohammad S
Contreras, Sandra
Medina, Francesc
Sueiras, Jesus
description Hydrogen peroxide formation is achieved with remarkable productivity at ambient conditions (25 degrees C and atmospheric pressure) in aqueous medium using a heterogeneous catalytic system; formic acid is decomposed in the presence of a continuous flow of O(2) over Pd/gamma-Al(2)O(3) catalyst leading to the generation of hydrogen peroxide; the addition of a negligible amount of bromide ion improves the selectivity of the reaction.
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title Direct generation of hydrogen peroxide from formic acid and O2 using heterogeneous Pd/gamma-Al2O3 catalysts
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