Poly(Biradicals): Oligomers of 1,3-Diphosphacyclobutane-2,4-diyl Units
Biradical chromophore bridge: Di‐ and trimethylenephenyl moieties facilitate a through‐space interaction between sterically demanding biradical subunits (see picture), enabling the design of new electronic materials. The solid‐state structure of a bis(biradical) derivative illustrates the proximal p...
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| Veröffentlicht in: | Angewandte Chemie (International ed.) 2008-08, Vol.47 (34), p.6418-6421 |
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| container_end_page | 6421 |
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| container_issue | 34 |
| container_start_page | 6418 |
| container_title | Angewandte Chemie (International ed.) |
| container_volume | 47 |
| creator | Ito, Shigekazu Miura, Joji Morita, Noboru Yoshifuji, Masaaki Arduengo, Anthony J. III |
| description | Biradical chromophore bridge: Di‐ and trimethylenephenyl moieties facilitate a through‐space interaction between sterically demanding biradical subunits (see picture), enabling the design of new electronic materials. The solid‐state structure of a bis(biradical) derivative illustrates the proximal positioning of two biradical subunits, allowing for direct interaction between them. |
| doi_str_mv | 10.1002/anie.200801461 |
| format | Article |
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| identifier | ISSN: 1433-7851 |
| ispartof | Angewandte Chemie (International ed.), 2008-08, Vol.47 (34), p.6418-6421 |
| issn | 1433-7851 1521-3773 |
| language | eng |
| recordid | cdi_proquest_miscellaneous_69422018 |
| source | Wiley Online Library Journals Frontfile Complete |
| subjects | biradicals conformational analysis electrochemistry phosphorus heterocycles steric hindrance |
| title | Poly(Biradicals): Oligomers of 1,3-Diphosphacyclobutane-2,4-diyl Units |
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