Phosphorous Acid and Urea: Valuable Sources of Phosphorus and Nitrogen in the Hydrothermal Synthesis of Ammonium-Thorium Phosphates

Phosphorous Acid and Urea: Valuable Sources of Phosphorus and Nitrogen in the Hydrothermal Synthesis of Ammonium-Thorium Phosphates

Microcrystals of the first ammonium-thorium phosphates, (NH4)2Th(PO4)2·H2O (tetragonal, I41/amd, a = 7.0192(4) Å, c = 17.9403(8) Å) and NH4Th2(PO4)3 (monoclinic, C2/c, a = 17.880(6) Å, b = 6.906(1) Å, c = 8.152(2) Å, β = 104.39(2)°) were hydrothermally obtained from a Th(NO3)4-CO(NH2)2-H3PO3-H2O sys...

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Veröffentlicht in:Inorganic chemistry 2008-08, Vol.47 (16), p.7207-7210
Hauptverfasser: Salvadó, Miguel A, Pertierra, Pilar, Bortun, Anatoly I, Trobajo, Camino, García, José R
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container_end_page 7210
container_issue 16
container_start_page 7207
container_title Inorganic chemistry
container_volume 47
creator Salvadó, Miguel A
Pertierra, Pilar
Bortun, Anatoly I
Trobajo, Camino
García, José R
description Microcrystals of the first ammonium-thorium phosphates, (NH4)2Th(PO4)2·H2O (tetragonal, I41/amd, a = 7.0192(4) Å, c = 17.9403(8) Å) and NH4Th2(PO4)3 (monoclinic, C2/c, a = 17.880(6) Å, b = 6.906(1) Å, c = 8.152(2) Å, β = 104.39(2)°) were hydrothermally obtained from a Th(NO3)4-CO(NH2)2-H3PO3-H2O system (T = 180 °C). In both cases, the structure consists of a three-dimensional framework with PO4 tetrahedra coordinated to Th atoms (ThO n polyhedra, where n = 8 or 9, for the tetragonal or monoclinic phase, respectively). The ammonium ions (and water molecules) are located in the tunnels.
doi_str_mv 10.1021/ic800818c
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title Phosphorous Acid and Urea: Valuable Sources of Phosphorus and Nitrogen in the Hydrothermal Synthesis of Ammonium-Thorium Phosphates
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