3D Framework Containing Cu4Br4 Cubane as Connecting Node with Strong Ferroelectricity
The methanolothermal reaction of (S)-1,4-diallyl-2-methylpiperazine (DAMP) with an excess CuBr affords a novel homochiral 3D framework (DAMP)3(Cu4Br4)2(H2O)3 (1) in which Cu4Br4 cubane acts as a connecting node to mimic the pure inorganic role in the ferroelectricity to enhance the remnant polarizat...
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| Veröffentlicht in: | Journal of the American Chemical Society 2008-08, Vol.130 (32), p.10468-10469 |
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| container_end_page | 10469 |
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| container_issue | 32 |
| container_start_page | 10468 |
| container_title | Journal of the American Chemical Society |
| container_volume | 130 |
| creator | Zhang, Wen Xiong, Ren-Gen Huang, Songping D |
| description | The methanolothermal reaction of (S)-1,4-diallyl-2-methylpiperazine (DAMP) with an excess CuBr affords a novel homochiral 3D framework (DAMP)3(Cu4Br4)2(H2O)3 (1) in which Cu4Br4 cubane acts as a connecting node to mimic the pure inorganic role in the ferroelectricity to enhance the remnant polarization value which is comparable to that of BaTiO3 synthesized by peptide-assisted synthesis. |
| doi_str_mv | 10.1021/ja803021v |
| format | Article |
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| ispartof | Journal of the American Chemical Society, 2008-08, Vol.130 (32), p.10468-10469 |
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| language | eng |
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| source | American Chemical Society Journals |
| title | 3D Framework Containing Cu4Br4 Cubane as Connecting Node with Strong Ferroelectricity |
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