Clarification of the Oxidation State of Cobalt Corroles in Heterogeneous and Homogeneous Catalytic Reduction of Dioxygen

Co(III) corroles were investigated as efficient catalysts for the reduction of dioxygen in the presence of perchloric acid in both heterogeneous and homogeneous systems. The investigated compounds are (5,10,15-tris(pentafluorophenyl)corrole)cobalt (TPFCor)Co, (10-pentafluorophenyl-5,15-dimesitylcorr...

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Veröffentlicht in:	Inorganic chemistry 2008-08, Vol.47 (15), p.6726-6737
Hauptverfasser:	Kadish, Karl M, Shen, Jing, Frémond, Laurent, Chen, Ping, Ojaimi, Maya El, Chkounda, Mohammed, Gros, Claude P, Barbe, Jean-Michel, Ohkubo, Kei, Fukuzumi, Shunichi, Guilard, Roger
Format:	Artikel
Sprache:	eng
Schlagworte:	Catalysis Catalysts Cobalt - chemistry Electrochemistry Electrodes Electron Spin Resonance Spectroscopy Graphite Organometallic Compounds - chemistry Oxidation-Reduction Oxygen - chemistry Perchlorates - chemistry Perchloric acid Porphyrins - chemistry Reduction Spectrophotometry, Ultraviolet Surface chemistry Voltammetry
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