Ruthenium-Catalyzed Selective and Efficient Oxygenation of Hydrocarbons with Water as an Oxygen Source

Water is not only the solvent but also the sole oxygen source in the smooth and efficient oxidation of organic compounds catalyzed by a RuII–pyridylamine–aqua complex with CeIV as the oxidant. An intermediate‐spin RuIV–oxo complex is formed as the reactive species (see scheme; Sub=substrate). This c...

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Veröffentlicht in:	Angewandte Chemie (International ed.) 2008-07, Vol.47 (31), p.5772-5776
Hauptverfasser:	Hirai, Yuichirou, Kojima, Takahiko, Mizutani, Yasuhisa, Shiota, Yoshihito, Yoshizawa, Kazunari, Fukuzumi, Shunichi
Format:	Artikel
Sprache:	eng
Schlagworte:	cerium homogeneous catalysis oxidation redox chemistry ruthenium
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container_title	Angewandte Chemie (International ed.)
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creator	Hirai, Yuichirou Kojima, Takahiko Mizutani, Yasuhisa Shiota, Yoshihito Yoshizawa, Kazunari Fukuzumi, Shunichi
description	Water is not only the solvent but also the sole oxygen source in the smooth and efficient oxidation of organic compounds catalyzed by a RuII–pyridylamine–aqua complex with CeIV as the oxidant. An intermediate‐spin RuIV–oxo complex is formed as the reactive species (see scheme; Sub=substrate). This catalytic system is durable and able to gain high turnover numbers for various substrates.
doi_str_mv	10.1002/anie.200801170
format	Article
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source	Wiley Online Library Journals Frontfile Complete
subjects	cerium homogeneous catalysis oxidation redox chemistry ruthenium
title	Ruthenium-Catalyzed Selective and Efficient Oxygenation of Hydrocarbons with Water as an Oxygen Source
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