Synthesis and study of the cluster [Pd(AuPPh 3) 6(HgNO 3)](NO 3) by reversed-phase high-performance liquid chromatography, thermoanalysis, infrared, nuclear magnetic resonance, and fast atom bombardment mass spectrometry
The addition reaction of Hg 0 and Hg 2 2+ to the bimetallic cluster [(PPh 3)Pd(AuPPh 3) 6](NO 3) 2 (I) has been studied. The reaction, monitored by HPLC, showed the time elapsed to obtain the pure cluster [Pd(AuPPh 3) 6(HgNO 3)](NO 3) (II). The use of 31P{ 1H} NMR, IR spectra, FABMS and thermoanalys...
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| Veröffentlicht in: | Journal of Chromatography A 1999-11, Vol.862 (1), p.29-38 |
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| container_title | Journal of Chromatography A |
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| creator | Sotelo, Adriana F Felicissimo, Anna Maria P |
| description | The addition reaction of Hg
0 and Hg
2
2+ to the bimetallic cluster [(PPh
3)Pd(AuPPh
3)
6](NO
3)
2
(I) has been studied. The reaction, monitored by HPLC, showed the time elapsed to obtain the pure cluster [Pd(AuPPh
3)
6(HgNO
3)](NO
3)
(II). The use of
31P{
1H} NMR, IR spectra, FABMS and thermoanalysis data was very useful for confirming the results. The reaction was monitored by taking five samples after 3, 6, 17, 21 and 24 h. The process was finalised after 24 h and the pure trimetallic cluster
II, free of the intermediate, appeared in the chromatogram as a large, unique peak. |
| doi_str_mv | 10.1016/S0021-9673(99)00913-9 |
| format | Article |
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0 and Hg
2
2+ to the bimetallic cluster [(PPh
3)Pd(AuPPh
3)
6](NO
3)
2
(I) has been studied. The reaction, monitored by HPLC, showed the time elapsed to obtain the pure cluster [Pd(AuPPh
3)
6(HgNO
3)](NO
3)
(II). The use of
31P{
1H} NMR, IR spectra, FABMS and thermoanalysis data was very useful for confirming the results. The reaction was monitored by taking five samples after 3, 6, 17, 21 and 24 h. The process was finalised after 24 h and the pure trimetallic cluster
II, free of the intermediate, appeared in the chromatogram as a large, unique peak.</description><identifier>ISSN: 0021-9673</identifier><identifier>DOI: 10.1016/S0021-9673(99)00913-9</identifier><identifier>PMID: 10588338</identifier><identifier>CODEN: JOCRAM</identifier><language>eng</language><publisher>Amsterdam: Elsevier B.V</publisher><subject>Chemistry ; Chromatography, High Pressure Liquid ; Coordination compounds ; Exact sciences and technology ; Gold clusters ; Hot Temperature ; Inorganic chemistry and origins of life ; Magnetic Resonance Spectroscopy ; Organometallic Compounds - chemical synthesis ; Palladium–gold ; Phosphine ; Preparations and properties ; Spectrometry, Mass, Fast Atom Bombardment ; Spectrophotometry, Infrared ; Time Factors</subject><ispartof>Journal of Chromatography A, 1999-11, Vol.862 (1), p.29-38</ispartof><rights>1999 Elsevier Science B.V.</rights><rights>2000 INIST-CNRS</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c390t-346990095563f0a351ad507d2762001f1a3b2ee3e9fe95169b63fb3fe101d4073</citedby><cites>FETCH-LOGICAL-c390t-346990095563f0a351ad507d2762001f1a3b2ee3e9fe95169b63fb3fe101d4073</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://dx.doi.org/10.1016/S0021-9673(99)00913-9$$EHTML$$P50$$Gelsevier$$H</linktohtml><link.rule.ids>314,780,784,3550,27924,27925,45995</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=1207340$$DView record in Pascal Francis$$Hfree_for_read</backlink><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/10588338$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Sotelo, Adriana F</creatorcontrib><creatorcontrib>Felicissimo, Anna Maria P</creatorcontrib><title>Synthesis and study of the cluster [Pd(AuPPh 3) 6(HgNO 3)](NO 3) by reversed-phase high-performance liquid chromatography, thermoanalysis, infrared, nuclear magnetic resonance, and fast atom bombardment mass spectrometry</title><title>Journal of Chromatography A</title><addtitle>J Chromatogr A</addtitle><description>The addition reaction of Hg
0 and Hg
2
2+ to the bimetallic cluster [(PPh
3)Pd(AuPPh
3)
6](NO
3)
2
(I) has been studied. The reaction, monitored by HPLC, showed the time elapsed to obtain the pure cluster [Pd(AuPPh
3)
6(HgNO
3)](NO
3)
(II). The use of
31P{
1H} NMR, IR spectra, FABMS and thermoanalysis data was very useful for confirming the results. The reaction was monitored by taking five samples after 3, 6, 17, 21 and 24 h. The process was finalised after 24 h and the pure trimetallic cluster
II, free of the intermediate, appeared in the chromatogram as a large, unique peak.</description><subject>Chemistry</subject><subject>Chromatography, High Pressure Liquid</subject><subject>Coordination compounds</subject><subject>Exact sciences and technology</subject><subject>Gold clusters</subject><subject>Hot Temperature</subject><subject>Inorganic chemistry and origins of life</subject><subject>Magnetic Resonance Spectroscopy</subject><subject>Organometallic Compounds - chemical synthesis</subject><subject>Palladium–gold</subject><subject>Phosphine</subject><subject>Preparations and properties</subject><subject>Spectrometry, Mass, Fast Atom Bombardment</subject><subject>Spectrophotometry, Infrared</subject><subject>Time Factors</subject><issn>0021-9673</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>1999</creationdate><recordtype>article</recordtype><sourceid>EIF</sourceid><recordid>eNqFkc9u1DAQxnMA0VJ4BJAPCG2lDdjxJlmfqqqCFqmiKxVOCFmOPdkYJXbqcSrlXXkYvH9UuHGa0eg3842-L8veMPqBUVZ9vKe0YLmoar4Q4pxSwXgunmWnT-OT7CXiL0pZTeviRXbCaLlec74-zX7fzy52gBaJcoZgnMxMfEvSjOh-wgiB_NiYxeW02XSEn5NqcbP9epe6n4t9Ic1MAjxCQDD52CkE0tltl48QWh8G5TSQ3j5M1hDdBT-o6LdBjd283GmEwSun-jnpL4l1bVABzJK4SfegAhnU1kG0Oimgd7tby_2brcJI0qWBNH5oVDADuJhoRIIj6Jh0IIb5Vfa8VT3C62M9y75__vTt6ia_vbv-cnV5m2suaMz5qhIiuVaWFW-p4iVTpqS1KeqqSJ61TPGmAOAgWhAlq0STuIa3kMw3K1rzs-z94e4Y_MMEGOVgUUPfKwd-QlkJzldryhJYHkAdPGKAVo7BDirMklG5i1Luo5S7zKQQch-lFGnv7VFgagYw_2wdckzAuyOgUKs--ei0xb9ckb5c0YRdHDBIbjxaCBK1hWSrsSHZJo23__nkD1v0vzo</recordid><startdate>19991105</startdate><enddate>19991105</enddate><creator>Sotelo, Adriana F</creator><creator>Felicissimo, Anna Maria P</creator><general>Elsevier B.V</general><general>Elsevier</general><scope>IQODW</scope><scope>CGR</scope><scope>CUY</scope><scope>CVF</scope><scope>ECM</scope><scope>EIF</scope><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7X8</scope></search><sort><creationdate>19991105</creationdate><title>Synthesis and study of the cluster [Pd(AuPPh 3) 6(HgNO 3)](NO 3) by reversed-phase high-performance liquid chromatography, thermoanalysis, infrared, nuclear magnetic resonance, and fast atom bombardment mass spectrometry</title><author>Sotelo, Adriana F ; Felicissimo, Anna Maria P</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c390t-346990095563f0a351ad507d2762001f1a3b2ee3e9fe95169b63fb3fe101d4073</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>1999</creationdate><topic>Chemistry</topic><topic>Chromatography, High Pressure Liquid</topic><topic>Coordination compounds</topic><topic>Exact sciences and technology</topic><topic>Gold clusters</topic><topic>Hot Temperature</topic><topic>Inorganic chemistry and origins of life</topic><topic>Magnetic Resonance Spectroscopy</topic><topic>Organometallic Compounds - chemical synthesis</topic><topic>Palladium–gold</topic><topic>Phosphine</topic><topic>Preparations and properties</topic><topic>Spectrometry, Mass, Fast Atom Bombardment</topic><topic>Spectrophotometry, Infrared</topic><topic>Time Factors</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Sotelo, Adriana F</creatorcontrib><creatorcontrib>Felicissimo, Anna Maria P</creatorcontrib><collection>Pascal-Francis</collection><collection>Medline</collection><collection>MEDLINE</collection><collection>MEDLINE (Ovid)</collection><collection>MEDLINE</collection><collection>MEDLINE</collection><collection>PubMed</collection><collection>CrossRef</collection><collection>MEDLINE - Academic</collection><jtitle>Journal of Chromatography A</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Sotelo, Adriana F</au><au>Felicissimo, Anna Maria P</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Synthesis and study of the cluster [Pd(AuPPh 3) 6(HgNO 3)](NO 3) by reversed-phase high-performance liquid chromatography, thermoanalysis, infrared, nuclear magnetic resonance, and fast atom bombardment mass spectrometry</atitle><jtitle>Journal of Chromatography A</jtitle><addtitle>J Chromatogr A</addtitle><date>1999-11-05</date><risdate>1999</risdate><volume>862</volume><issue>1</issue><spage>29</spage><epage>38</epage><pages>29-38</pages><issn>0021-9673</issn><coden>JOCRAM</coden><abstract>The addition reaction of Hg
0 and Hg
2
2+ to the bimetallic cluster [(PPh
3)Pd(AuPPh
3)
6](NO
3)
2
(I) has been studied. The reaction, monitored by HPLC, showed the time elapsed to obtain the pure cluster [Pd(AuPPh
3)
6(HgNO
3)](NO
3)
(II). The use of
31P{
1H} NMR, IR spectra, FABMS and thermoanalysis data was very useful for confirming the results. The reaction was monitored by taking five samples after 3, 6, 17, 21 and 24 h. The process was finalised after 24 h and the pure trimetallic cluster
II, free of the intermediate, appeared in the chromatogram as a large, unique peak.</abstract><cop>Amsterdam</cop><pub>Elsevier B.V</pub><pmid>10588338</pmid><doi>10.1016/S0021-9673(99)00913-9</doi><tpages>10</tpages></addata></record> |
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| issn | 0021-9673 |
| language | eng |
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| source | MEDLINE; Access via ScienceDirect (Elsevier) |
| subjects | Chemistry Chromatography, High Pressure Liquid Coordination compounds Exact sciences and technology Gold clusters Hot Temperature Inorganic chemistry and origins of life Magnetic Resonance Spectroscopy Organometallic Compounds - chemical synthesis Palladium–gold Phosphine Preparations and properties Spectrometry, Mass, Fast Atom Bombardment Spectrophotometry, Infrared Time Factors |
| title | Synthesis and study of the cluster [Pd(AuPPh 3) 6(HgNO 3)](NO 3) by reversed-phase high-performance liquid chromatography, thermoanalysis, infrared, nuclear magnetic resonance, and fast atom bombardment mass spectrometry |
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