On the Quest for New Mixed-Metal μ-Oxo-bridged Complexes: Synthesis of Compounds Containing Transition Metal−Oxygen−Main Group Metal Motifs M−O−M1 (M = Ti, Zr; M1 = Al, Ga) without Cyclopentadienyl Ligands

The reaction of TiBz4 (Bz = benzyl) with LAlMe(OH), L = (2,6-iPr2C6H3NC(Me))2CH, afforded LAlMe(μ-O)TiBz3 (1) and [LAlMe(μ-O)]2TiBz2 (2), whereas the corresponding reaction with ZrBz4 resulted only in the formation of the trinuclear species [LAlMe(μ-O)]2ZrBz2 (3). The reaction of (Mes2Ga(OH))2·THF (...

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Veröffentlicht in:	Inorganic chemistry 2008-07, Vol.47 (14), p.6435-6443
Hauptverfasser:	Nikiforov, Grigory B, Roesky, Herbert W, Schulz, Thomas, Stalke, Dietmar, Witt, M
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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