Supercritical Secondary Alcohols as Useful Media To Convert Polyamide into Monomeric Lactams
Towards sustainable stockings? Nylon 6 was efficiently converted into its monomer caprolactam, which was isolated in over 90 % yield with excellent purity as the sole product of the reaction, by treatment with supercritical secondary or tertiary alcohols. The present method opens up a new avenue in...
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| Veröffentlicht in: | ChemSusChem 2008-02, Vol.1 (1-2), p.82-84 |
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| container_title | ChemSusChem |
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| creator | Kamimura, Akio Oishi, Yusuke Kaiso, Kouji Sugimoto, Tsunemi Kashiwagi, Kohichi |
| description | Towards sustainable stockings? Nylon 6 was efficiently converted into its monomer caprolactam, which was isolated in over 90 % yield with excellent purity as the sole product of the reaction, by treatment with supercritical secondary or tertiary alcohols. The present method opens up a new avenue in plastic recycling chemistry. |
| doi_str_mv | 10.1002/cssc.200700024 |
| format | Article |
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Nylon 6 was efficiently converted into its monomer caprolactam, which was isolated in over 90 % yield with excellent purity as the sole product of the reaction, by treatment with supercritical secondary or tertiary alcohols. 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| fulltext | fulltext |
| identifier | ISSN: 1864-5631 |
| ispartof | ChemSusChem, 2008-02, Vol.1 (1-2), p.82-84 |
| issn | 1864-5631 1864-564X |
| language | eng |
| recordid | cdi_proquest_miscellaneous_69294116 |
| source | MEDLINE; Wiley Online Library Journals Frontfile Complete |
| subjects | Alcohols - chemistry Caprolactam - analogs & derivatives Caprolactam - chemistry high-pressure chemistry high-temperature chemistry Lactams - chemistry Nylons - chemistry polymers Polymers - chemistry solvolysis supercritical fluids Temperature |
| title | Supercritical Secondary Alcohols as Useful Media To Convert Polyamide into Monomeric Lactams |
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