A new type of mixed anionic framework in microporous rubidium copper vanadyl(V) phosphate, Rb2Cu(VO2)2(PO4)2
In dirubidium copper bis[vanadyl(V)] bis(phosphate), Rb2Cu(VO2)2(PO4)2, three different oxo complexes form an anionic framework. VO5 polyhedra in a trigonal bipyramidal configuration and PO4 tetrahedra share vertices to form eight‐membered rings, which lie in layers perpendicular to the a axis of th...
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| Veröffentlicht in: | Acta crystallographica. Section C, Crystal structure communications Crystal structure communications, 2008-07, Vol.64 (7), p.i62-i65 |
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| container_title | Acta crystallographica. Section C, Crystal structure communications |
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| creator | Yakubovich, Olga V. Steele, Ian M. Dimitrova, Olga V. |
| description | In dirubidium copper bis[vanadyl(V)] bis(phosphate), Rb2Cu(VO2)2(PO4)2, three different oxo complexes form an anionic framework. VO5 polyhedra in a trigonal bipyramidal configuration and PO4 tetrahedra share vertices to form eight‐membered rings, which lie in layers perpendicular to the a axis of the monoclinic unit cell. Cu atoms at centres of symmetry have square‐planar coordination and link these layers along [100] to form a three‐dimensional anionic framework, viz. [Cu(VO2)2(PO4)2]∞2−. Intersecting channels in the [100], [001] and [011] directions contain Rb+ cations. Topological relations between this new structure type and the crystal structures of A(VO2)(PO4) (A = Ba, Sr or Pb) and BaCrF2LiF4 are discussed. |
| doi_str_mv | 10.1107/S0108270108016454 |
| format | Article |
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VO5 polyhedra in a trigonal bipyramidal configuration and PO4 tetrahedra share vertices to form eight‐membered rings, which lie in layers perpendicular to the a axis of the monoclinic unit cell. Cu atoms at centres of symmetry have square‐planar coordination and link these layers along [100] to form a three‐dimensional anionic framework, viz. [Cu(VO2)2(PO4)2]∞2−. Intersecting channels in the [100], [001] and [011] directions contain Rb+ cations. Topological relations between this new structure type and the crystal structures of A(VO2)(PO4) (A = Ba, Sr or Pb) and BaCrF2LiF4 are discussed.</description><identifier>ISSN: 0108-2701</identifier><identifier>EISSN: 1600-5759</identifier><identifier>DOI: 10.1107/S0108270108016454</identifier><identifier>PMID: 18599967</identifier><language>eng</language><publisher>5 Abbey Square, Chester, Cheshire CH1 2HU, England: International Union of Crystallography</publisher><subject>Comparative studies ; Copper ; Crystal structure ; Crystallography ; Polyhedra</subject><ispartof>Acta crystallographica. 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Topological relations between this new structure type and the crystal structures of A(VO2)(PO4) (A = Ba, Sr or Pb) and BaCrF2LiF4 are discussed.</description><subject>Comparative studies</subject><subject>Copper</subject><subject>Crystal structure</subject><subject>Crystallography</subject><subject>Polyhedra</subject><issn>0108-2701</issn><issn>1600-5759</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2008</creationdate><recordtype>article</recordtype><recordid>eNqFkc1u1DAUhS0EokPLA7BBFotqRiLFv3G8HCLaUlUdKFAEG8txblS3SRycCdN5exJNAYku2NiSz3eO7vVB6AUlR5QS9eYToSRjajoJTYUUj9CMpoQkUkn9GM0mIZn0PfSs728IIYwx_hTt0UxqrVM1Q_USt7DB620HOFS48XdQYtv60HqHq2gb2IR4i307Si6GLsQw9DgOhS_90GAXug4i_mlbW27r-dUCd9eh767tGl7jy4Llw_xqxRZs_mElFuwAPals3cPz-3sffTl-9zk_Tc5XJ-_z5XniqdYqYaWV2pWOVTwDUrFCVRXRlpQFMAmgVZVpQVQBjoEAZ10pHC2LlFGr-PjC99HhLreL4ccA_do0vndQ17aFcXyTapZJRdR_QS54xqSWI_jqH_AmDLEdlzCMcCoEZxP08h4aigZK00Xf2Lg1v397BLIdsPE1bP_qxEx1mgd1muW3_Hg5xk_WZGf1_Rru_lhtvDVjsJLm68WJeXt59v30Y87NGf8F9gmgAw</recordid><startdate>200807</startdate><enddate>200807</enddate><creator>Yakubovich, Olga V.</creator><creator>Steele, Ian M.</creator><creator>Dimitrova, Olga V.</creator><general>International Union of Crystallography</general><general>Wiley Subscription Services, Inc</general><scope>BSCLL</scope><scope>NPM</scope><scope>7SR</scope><scope>7U5</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>L7M</scope><scope>7X8</scope></search><sort><creationdate>200807</creationdate><title>A new type of mixed anionic framework in microporous rubidium copper vanadyl(V) phosphate, Rb2Cu(VO2)2(PO4)2</title><author>Yakubovich, Olga V. ; Steele, Ian M. ; Dimitrova, Olga V.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-i1997-2da59cdc2f38e0f2b7ff09a0dbe25ee97f89407bec2e4ecacd4c1db621a73e4e3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2008</creationdate><topic>Comparative studies</topic><topic>Copper</topic><topic>Crystal structure</topic><topic>Crystallography</topic><topic>Polyhedra</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Yakubovich, Olga V.</creatorcontrib><creatorcontrib>Steele, Ian M.</creatorcontrib><creatorcontrib>Dimitrova, Olga V.</creatorcontrib><collection>Istex</collection><collection>PubMed</collection><collection>Engineered Materials Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><collection>MEDLINE - Academic</collection><jtitle>Acta crystallographica. Section C, Crystal structure communications</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Yakubovich, Olga V.</au><au>Steele, Ian M.</au><au>Dimitrova, Olga V.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>A new type of mixed anionic framework in microporous rubidium copper vanadyl(V) phosphate, Rb2Cu(VO2)2(PO4)2</atitle><jtitle>Acta crystallographica. Section C, Crystal structure communications</jtitle><addtitle>Acta Cryst. C</addtitle><date>2008-07</date><risdate>2008</risdate><volume>64</volume><issue>7</issue><spage>i62</spage><epage>i65</epage><pages>i62-i65</pages><issn>0108-2701</issn><eissn>1600-5759</eissn><abstract>In dirubidium copper bis[vanadyl(V)] bis(phosphate), Rb2Cu(VO2)2(PO4)2, three different oxo complexes form an anionic framework. VO5 polyhedra in a trigonal bipyramidal configuration and PO4 tetrahedra share vertices to form eight‐membered rings, which lie in layers perpendicular to the a axis of the monoclinic unit cell. Cu atoms at centres of symmetry have square‐planar coordination and link these layers along [100] to form a three‐dimensional anionic framework, viz. [Cu(VO2)2(PO4)2]∞2−. Intersecting channels in the [100], [001] and [011] directions contain Rb+ cations. Topological relations between this new structure type and the crystal structures of A(VO2)(PO4) (A = Ba, Sr or Pb) and BaCrF2LiF4 are discussed.</abstract><cop>5 Abbey Square, Chester, Cheshire CH1 2HU, England</cop><pub>International Union of Crystallography</pub><pmid>18599967</pmid><doi>10.1107/S0108270108016454</doi></addata></record> |
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| identifier | ISSN: 0108-2701 |
| ispartof | Acta crystallographica. Section C, Crystal structure communications, 2008-07, Vol.64 (7), p.i62-i65 |
| issn | 0108-2701 1600-5759 |
| language | eng |
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| source | Wiley Online Library Journals Frontfile Complete; Alma/SFX Local Collection |
| subjects | Comparative studies Copper Crystal structure Crystallography Polyhedra |
| title | A new type of mixed anionic framework in microporous rubidium copper vanadyl(V) phosphate, Rb2Cu(VO2)2(PO4)2 |
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