Kinetic Gate-Opening Process in a Flexible Porous Coordination Polymer

Open the gate! A porous coordination polymer shows abrupt changes in its adsorption isotherm with guest‐dependent gate‐opening pressure (see picture). Kinetic analysis reveals that adsorption with structure transformation follows a gate‐opening model, in which adsorption proceeds through the formati...

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Veröffentlicht in:	Angewandte Chemie (International ed.) 2008-01, Vol.47 (21), p.3914-3918
Hauptverfasser:	Tanaka, Daisuke, Nakagawa, Keiji, Higuchi, Masakazu, Horike, Satoshi, Kubota, Yoshiki, Kobayashi, Tatsuo C, Takata, Masaki, Kitagawa, Susumu
Format:	Artikel
Sprache:	eng
Schlagworte:	adsorption coordination polymers kinetics microporous materials phase transitions
Online-Zugang:	Volltext
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