High resolution probe of spin-orbit coupling and the singlet-triplet gap in chlorocarbene

Among the most important of chemical intermediates are the carbenes, characterized by a divalent carbon that generates low-lying biradical (triplet) and spin-paired (singlet) configurations with unique chemical reactivities. The "holy grail" of carbene chemistry has been determining the si...

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Veröffentlicht in:	The Journal of chemical physics 2008-05, Vol.128 (17), p.171101-171101
Hauptverfasser:	Tao, Chong, Mukarakate, Calvin, Judge, Richard H, Reid, Scott A
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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