Calorimetric study of correlated disordering in [Hdamel]2[Cu(II)(tdpd)2] x 2 THF crystal

The heat capacity of [Hdamel]2[Cu(II)(tdpd)2] x 2 THF was measured from 6 to 250 K by adiabatic calorimetry. There are four heat anomalies around 150 K associated with disordering in the orientation of the uncoordinated THF molecules and in the conformation of the out-of-plane allyl groups of [Hdame...

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Veröffentlicht in:The journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment, & general theory Molecules, spectroscopy, kinetics, environment, & general theory, 2008-05, Vol.112 (19), p.4465-4469
Hauptverfasser: Yamamura, Yasuhisa, Shimoi, Hiroyasu, Sumita, Masato, Yasuzuka, Syuma, Adachi, Keiichi, Fuyuhiro, Akira, Kawata, Satoshi, Saito, Kazuya
Format: Artikel
Sprache:eng
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