Liquid Azide Salts

Ionic liquid azides from azidoethyl, alkyl, and alkenyl substituted derivatives of 1,2,4- and 1,2,3-amino-triazoles were prepared and examined for the first time to investigate their structural and physical properties. All reported salts possess melting points below 100 °C. The unique character of t...

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Veröffentlicht in:	Inorganic chemistry 2008-05, Vol.47 (9), p.3617-3624
Hauptverfasser:	Schneider, Stefan, Hawkins, Tommy, Rosander, Michael, Mills, Jeffrey, Brand, Adam, Hudgens, Leslie, Warmoth, Greg, Vij, Ashwani
Format:	Artikel
Sprache:	eng
Schlagworte:	Azides (inorganic) Derivatives Ionic liquids Liquids Melting points Physical properties Thermal stability Volatility
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creator	Schneider, Stefan Hawkins, Tommy Rosander, Michael Mills, Jeffrey Brand, Adam Hudgens, Leslie Warmoth, Greg Vij, Ashwani
description	Ionic liquid azides from azidoethyl, alkyl, and alkenyl substituted derivatives of 1,2,4- and 1,2,3-amino-triazoles were prepared and examined for the first time to investigate their structural and physical properties. All reported salts possess melting points below 100 °C. The unique character of these newly discovered ionic liquid azides is based upon the fact that these molecules are not simple protonated salts like previously reported substituted hydrazinium azides. The presence of quaternary nitrogen confers both thermal stability and negligible volatility.
doi_str_mv	10.1021/ic702068r
format	Article
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All reported salts possess melting points below 100 °C. The unique character of these newly discovered ionic liquid azides is based upon the fact that these molecules are not simple protonated salts like previously reported substituted hydrazinium azides. 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Chem</addtitle><date>2008-05-05</date><risdate>2008</risdate><volume>47</volume><issue>9</issue><spage>3617</spage><epage>3624</epage><pages>3617-3624</pages><issn>0020-1669</issn><eissn>1520-510X</eissn><abstract>Ionic liquid azides from azidoethyl, alkyl, and alkenyl substituted derivatives of 1,2,4- and 1,2,3-amino-triazoles were prepared and examined for the first time to investigate their structural and physical properties. All reported salts possess melting points below 100 °C. The unique character of these newly discovered ionic liquid azides is based upon the fact that these molecules are not simple protonated salts like previously reported substituted hydrazinium azides. The presence of quaternary nitrogen confers both thermal stability and negligible volatility.</abstract><cop>United States</cop><pub>American Chemical Society</pub><pmid>18345619</pmid><doi>10.1021/ic702068r</doi><tpages>8</tpages></addata></record>
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subjects	Azides (inorganic) Derivatives Ionic liquids Liquids Melting points Physical properties Thermal stability Volatility
title	Liquid Azide Salts
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