Comparative studies on the solvent extraction of transition metal cations by calixarene, phenol and ester derivatives
The ionophore solvent extraction of various alkali metal and transition metal cations from the aqueous phase to the organic phase was carried out by using diazo-coupling calix[ n]arenes [ p-(4-phenylazophenylazo)calix[4]arene ( L1) and p-phenylazocalix[6]arene ( L2)], phenol derivatives [2,6-dimethy...
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| Veröffentlicht in: | Journal of hazardous materials 2008-06, Vol.154 (1), p.29-32 |
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| creator | Deligöz, Hasalettin Erdem, Emin |
| description | The ionophore solvent extraction of various alkali metal and transition metal cations from the aqueous phase to the organic phase was carried out by using diazo-coupling calix[
n]arenes [
p-(4-phenylazophenylazo)calix[4]arene (
L1) and
p-phenylazocalix[6]arene (
L2)], phenol derivatives [2,6-dimethyl-3-phenylazophenol (
L3), 2-(5-bromo-2-pyridylazo)-5-diethylamino phenol (
L4), 2-chloro-4-nitro(phenylazo)-5-
sec-butyl-2-phenol (
L5) and 2-chloro-4-nitro(phenylazo)-5-
tert-butyl-2-phenol (
L6)], and ester derivatives [quinoline-8-benzoate (
L7), phenyl-1,4-dibenzoate (
L8),
p-tolyltiobenzoate (
L9)]. It was found that, all the compounds (
L1–
L9) examined showed selectivity for transition metal cations such as Ag
+, Hg
+ Hg
2+, and poor efficiency for alkali metal cations (Na
+ and K
+). The best extraction efficiency was obtained with
L1 and
L4. |
| doi_str_mv | 10.1016/j.jhazmat.2007.09.096 |
| format | Article |
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n]arenes [
p-(4-phenylazophenylazo)calix[4]arene (
L1) and
p-phenylazocalix[6]arene (
L2)], phenol derivatives [2,6-dimethyl-3-phenylazophenol (
L3), 2-(5-bromo-2-pyridylazo)-5-diethylamino phenol (
L4), 2-chloro-4-nitro(phenylazo)-5-
sec-butyl-2-phenol (
L5) and 2-chloro-4-nitro(phenylazo)-5-
tert-butyl-2-phenol (
L6)], and ester derivatives [quinoline-8-benzoate (
L7), phenyl-1,4-dibenzoate (
L8),
p-tolyltiobenzoate (
L9)]. It was found that, all the compounds (
L1–
L9) examined showed selectivity for transition metal cations such as Ag
+, Hg
+ Hg
2+, and poor efficiency for alkali metal cations (Na
+ and K
+). The best extraction efficiency was obtained with
L1 and
L4.</description><identifier>ISSN: 0304-3894</identifier><identifier>EISSN: 1873-3336</identifier><identifier>DOI: 10.1016/j.jhazmat.2007.09.096</identifier><identifier>PMID: 17980958</identifier><identifier>CODEN: JHMAD9</identifier><language>eng</language><publisher>Amsterdam: Elsevier B.V</publisher><subject>Alkali metal ions ; Applied sciences ; Calixarenes - chemistry ; Chemical engineering ; Diazo compounds ; Diazo-coupling calyx[ n]arenes ( n = 4, 6) ; Esters - chemistry ; Exact sciences and technology ; Ligands ; Liquid-liquid extraction ; Metals - chemistry ; Phenols - chemistry ; Picrates - chemistry ; Pollution ; Solvent extraction ; Solvents - chemistry ; Transition metal ions</subject><ispartof>Journal of hazardous materials, 2008-06, Vol.154 (1), p.29-32</ispartof><rights>2007 Elsevier B.V.</rights><rights>2008 INIST-CNRS</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c521t-78c1c91cfbb71f89453b3b106a736b7c74d82b22dae1e2a7140009a5a6ba7ec93</citedby><cites>FETCH-LOGICAL-c521t-78c1c91cfbb71f89453b3b106a736b7c74d82b22dae1e2a7140009a5a6ba7ec93</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://dx.doi.org/10.1016/j.jhazmat.2007.09.096$$EHTML$$P50$$Gelsevier$$H</linktohtml><link.rule.ids>314,780,784,3550,27924,27925,45995</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=20324693$$DView record in Pascal Francis$$Hfree_for_read</backlink><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/17980958$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Deligöz, Hasalettin</creatorcontrib><creatorcontrib>Erdem, Emin</creatorcontrib><title>Comparative studies on the solvent extraction of transition metal cations by calixarene, phenol and ester derivatives</title><title>Journal of hazardous materials</title><addtitle>J Hazard Mater</addtitle><description>The ionophore solvent extraction of various alkali metal and transition metal cations from the aqueous phase to the organic phase was carried out by using diazo-coupling calix[
n]arenes [
p-(4-phenylazophenylazo)calix[4]arene (
L1) and
p-phenylazocalix[6]arene (
L2)], phenol derivatives [2,6-dimethyl-3-phenylazophenol (
L3), 2-(5-bromo-2-pyridylazo)-5-diethylamino phenol (
L4), 2-chloro-4-nitro(phenylazo)-5-
sec-butyl-2-phenol (
L5) and 2-chloro-4-nitro(phenylazo)-5-
tert-butyl-2-phenol (
L6)], and ester derivatives [quinoline-8-benzoate (
L7), phenyl-1,4-dibenzoate (
L8),
p-tolyltiobenzoate (
L9)]. It was found that, all the compounds (
L1–
L9) examined showed selectivity for transition metal cations such as Ag
+, Hg
+ Hg
2+, and poor efficiency for alkali metal cations (Na
+ and K
+). The best extraction efficiency was obtained with
L1 and
L4.</description><subject>Alkali metal ions</subject><subject>Applied sciences</subject><subject>Calixarenes - chemistry</subject><subject>Chemical engineering</subject><subject>Diazo compounds</subject><subject>Diazo-coupling calyx[ n]arenes ( n = 4, 6)</subject><subject>Esters - chemistry</subject><subject>Exact sciences and technology</subject><subject>Ligands</subject><subject>Liquid-liquid extraction</subject><subject>Metals - chemistry</subject><subject>Phenols - chemistry</subject><subject>Picrates - chemistry</subject><subject>Pollution</subject><subject>Solvent extraction</subject><subject>Solvents - chemistry</subject><subject>Transition metal ions</subject><issn>0304-3894</issn><issn>1873-3336</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2008</creationdate><recordtype>article</recordtype><sourceid>EIF</sourceid><recordid>eNqFkUuLFDEQx4Mo7rj6EZRc9GSPeXQnnZPI4AsWvOg5VNLVTIZ-jEl62PXTm9lp9DhQkKrwq-efkNecbTnj6sNhe9jDnxHyVjCmt8wUU0_IhrdaVlJK9ZRsmGR1JVtT35AXKR0YY1w39XNyw7VpmWnaDVl283iECDmckKa8dAETnSea9yWchxNOmeJ9juBzKN9zT4s_pfAYjZhhoB7OQaLuobhDuIeIE76nxz1O80Bh6iimjJF2GMPpsVF6SZ71MCR8tb635NeXzz9336q7H1-_7z7dVb4RPFe69dwb7nvnNO_LHo100nGmQEvltNd11wonRAfIUYDmdVnRQAPKgUZv5C15d6l7jPPvpYxhx5A8DgNMOC_JKsPrWrH2KiiF1kap6xW5Ua2UTBawuYA-zilF7O0xhhHig-XMnhW0B7sqaM8KWmaKqZL3Zm2wuBG7_1mrZAV4uwKQyr37IocP6R8nmBR1GbRwHy8clgOfAkabfMDJYxci-my7OVwZ5S-JDL6a</recordid><startdate>20080615</startdate><enddate>20080615</enddate><creator>Deligöz, Hasalettin</creator><creator>Erdem, Emin</creator><general>Elsevier B.V</general><general>Elsevier</general><scope>IQODW</scope><scope>CGR</scope><scope>CUY</scope><scope>CVF</scope><scope>ECM</scope><scope>EIF</scope><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7U7</scope><scope>C1K</scope><scope>8FD</scope><scope>FR3</scope><scope>KR7</scope><scope>7X8</scope></search><sort><creationdate>20080615</creationdate><title>Comparative studies on the solvent extraction of transition metal cations by calixarene, phenol and ester derivatives</title><author>Deligöz, Hasalettin ; Erdem, Emin</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c521t-78c1c91cfbb71f89453b3b106a736b7c74d82b22dae1e2a7140009a5a6ba7ec93</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2008</creationdate><topic>Alkali metal ions</topic><topic>Applied sciences</topic><topic>Calixarenes - chemistry</topic><topic>Chemical engineering</topic><topic>Diazo compounds</topic><topic>Diazo-coupling calyx[ n]arenes ( n = 4, 6)</topic><topic>Esters - chemistry</topic><topic>Exact sciences and technology</topic><topic>Ligands</topic><topic>Liquid-liquid extraction</topic><topic>Metals - chemistry</topic><topic>Phenols - chemistry</topic><topic>Picrates - chemistry</topic><topic>Pollution</topic><topic>Solvent extraction</topic><topic>Solvents - chemistry</topic><topic>Transition metal ions</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Deligöz, Hasalettin</creatorcontrib><creatorcontrib>Erdem, Emin</creatorcontrib><collection>Pascal-Francis</collection><collection>Medline</collection><collection>MEDLINE</collection><collection>MEDLINE (Ovid)</collection><collection>MEDLINE</collection><collection>MEDLINE</collection><collection>PubMed</collection><collection>CrossRef</collection><collection>Toxicology Abstracts</collection><collection>Environmental Sciences and Pollution Management</collection><collection>Technology Research Database</collection><collection>Engineering Research Database</collection><collection>Civil Engineering Abstracts</collection><collection>MEDLINE - Academic</collection><jtitle>Journal of hazardous materials</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Deligöz, Hasalettin</au><au>Erdem, Emin</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Comparative studies on the solvent extraction of transition metal cations by calixarene, phenol and ester derivatives</atitle><jtitle>Journal of hazardous materials</jtitle><addtitle>J Hazard Mater</addtitle><date>2008-06-15</date><risdate>2008</risdate><volume>154</volume><issue>1</issue><spage>29</spage><epage>32</epage><pages>29-32</pages><issn>0304-3894</issn><eissn>1873-3336</eissn><coden>JHMAD9</coden><abstract>The ionophore solvent extraction of various alkali metal and transition metal cations from the aqueous phase to the organic phase was carried out by using diazo-coupling calix[
n]arenes [
p-(4-phenylazophenylazo)calix[4]arene (
L1) and
p-phenylazocalix[6]arene (
L2)], phenol derivatives [2,6-dimethyl-3-phenylazophenol (
L3), 2-(5-bromo-2-pyridylazo)-5-diethylamino phenol (
L4), 2-chloro-4-nitro(phenylazo)-5-
sec-butyl-2-phenol (
L5) and 2-chloro-4-nitro(phenylazo)-5-
tert-butyl-2-phenol (
L6)], and ester derivatives [quinoline-8-benzoate (
L7), phenyl-1,4-dibenzoate (
L8),
p-tolyltiobenzoate (
L9)]. It was found that, all the compounds (
L1–
L9) examined showed selectivity for transition metal cations such as Ag
+, Hg
+ Hg
2+, and poor efficiency for alkali metal cations (Na
+ and K
+). The best extraction efficiency was obtained with
L1 and
L4.</abstract><cop>Amsterdam</cop><pub>Elsevier B.V</pub><pmid>17980958</pmid><doi>10.1016/j.jhazmat.2007.09.096</doi><tpages>4</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 0304-3894 |
| ispartof | Journal of hazardous materials, 2008-06, Vol.154 (1), p.29-32 |
| issn | 0304-3894 1873-3336 |
| language | eng |
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| source | MEDLINE; Access via ScienceDirect (Elsevier) |
| subjects | Alkali metal ions Applied sciences Calixarenes - chemistry Chemical engineering Diazo compounds Diazo-coupling calyx[ n]arenes ( n = 4, 6) Esters - chemistry Exact sciences and technology Ligands Liquid-liquid extraction Metals - chemistry Phenols - chemistry Picrates - chemistry Pollution Solvent extraction Solvents - chemistry Transition metal ions |
| title | Comparative studies on the solvent extraction of transition metal cations by calixarene, phenol and ester derivatives |
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