Et2Zn-Mediated Rearrangement of Bromohydrins

A simple and highly efficient method for the rearrangement of bromohydrins mediated by Et2Zn to synthesize carbonyl compounds was described. Various β-bromo alcohols were treated with 0.6 equiv of Et2Zn to form a zinc complex in CH2Cl2 at room temperature for 2 h, followed by 1,2-migration to give t...

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Veröffentlicht in:	Journal of organic chemistry 2008-05, Vol.73 (9), p.3516-3522
Hauptverfasser:	Li, Lezhen, Cai, Peijie, Guo, Qingxiang, Xue, Song
Format:	Artikel
Sprache:	eng
Schlagworte:	Alicyclic compounds Alicyclic compounds, terpenoids, prostaglandins, steroids Chemistry Exact sciences and technology Organic chemistry Preparations and properties
Online-Zugang:	Volltext
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