Ultraviolet upconversion emissions of Gd3

Under 980 nm excitation, upconversion (UC) emissions in the UV range of 270-320 nm were observed in nanocrystals Y(0.795-x)Gd(x)Yb(0.2)Tm(0.005)F(3) (x=0, 0.1, 0.2, 0.5, and 0.795), which were synthesized through a hydrothermal method. These UC emissions can be assigned to the transitions of (6)I(J)...

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Veröffentlicht in:Optics letters 2008-04, Vol.33 (8), p.857-859
Hauptverfasser: CHUNYAN CAO, WEIPING QIN, JISEN ZHANG, YAN WANG, PEIFEN ZHU, GUODONG WEI, GUOFENG WANG, KIM, Ryongjin, LILI WANG
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container_end_page 859
container_issue 8
container_start_page 857
container_title Optics letters
container_volume 33
creator CHUNYAN CAO
WEIPING QIN
JISEN ZHANG
YAN WANG
PEIFEN ZHU
GUODONG WEI
GUOFENG WANG
KIM, Ryongjin
LILI WANG
description Under 980 nm excitation, upconversion (UC) emissions in the UV range of 270-320 nm were observed in nanocrystals Y(0.795-x)Gd(x)Yb(0.2)Tm(0.005)F(3) (x=0, 0.1, 0.2, 0.5, and 0.795), which were synthesized through a hydrothermal method. These UC emissions can be assigned to the transitions of (6)I(J), (6)P(J)-->(8)S(7/2)(Gd(3+)), and (3)P(0)/(1)I(6)-->(3)H(6) (Tm(3+)). The energy transfer from Tm(3+) to Gd(3+) plays a crucial role in populating the excited states of Gd(3+). The shortest wavelength of upconverted emission converted from the infrared region was demonstrated here.
doi_str_mv 10.1364/OL.33.000857
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Fundamental areas of phenomenology (including applications)
Nonlinear optical crystals
Optical materials
Optics
Physics
title Ultraviolet upconversion emissions of Gd3
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