In Situ Hydrothermal Reduction of Neptunium(VI) as a Route to Neptunium(IV) Phosphonates

A lamellar neptunium(IV) methylphosphonate, Np(CH3PO3)(CH3PO3H)(NO3)(H2O)·H2O, has been prepared under hydrothermal conditions via the in situ reduction of NpVI to NpIV. The single crystal structure of this compound shows polar layers that are joined to one another via a hydrogen-bonding network inv...

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Veröffentlicht in:Inorganic chemistry 2007-12, Vol.46 (26), p.10959-10961
Hauptverfasser: Bray, Travis H, Nelson, Anna-Gay D, Jin, Geng Bang, Haire, Richard G, Albrecht-Schmitt, Thomas E
Format: Artikel
Sprache:eng
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