Ligands for Practical Rhodium-Catalyzed Asymmetric Hydroformylation

A series of bis-phosphite and bis-phosphine ligands for asymmetric hydroformylation reactions has been evaluated. Bis-phosphite ligands lead, in general, to high regioselectivities across a range of substrates while good enantioselectivities are limited to only a few examples. We found that bis-phos...

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Veröffentlicht in:	Accounts of chemical research 2007-12, Vol.40 (12), p.1251-1259
Hauptverfasser:	Klosin, Jerzy, Landis, Clark R
Format:	Artikel
Sprache:	eng
Schlagworte:	Aldehydes - chemical synthesis Aldehydes - chemistry Catalysis Hydrogenation Ligands Phosphorus Compounds - chemistry Rhodium - chemistry Stereoisomerism
Online-Zugang:	Volltext
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