Synthesis of Borondipyrromethene (BODIPY)-Labeled Sphingosine Derivatives by Cross-metathesis Reaction

A new efficient and flexible synthesis of fluorescently labeled sphingosine derivatives from commercially available Garner aldehyde (8) is described. For this, appropriate alkenylated borondipyrromethene (BODIPY) dyes were synthesized and used for the first time in a cross-metathesis reaction, the k...

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Veröffentlicht in:	Journal of organic chemistry 2007-03, Vol.72 (5), p.1842-1845
Hauptverfasser:	Peters, Carsten, Billich, Andreas, Ghobrial, Michael, Högenauer, Klemens, Ullrich, Thomas, Nussbaumer, Peter
Format:	Artikel
Sprache:	eng
Schlagworte:	Aldehydes - chemistry Boron Compounds - chemical synthesis Chemistry Chromatography, High Pressure Liquid Exact sciences and technology Fluorescent Dyes - chemical synthesis Fluorescent Dyes - chemistry Indicators and Reagents Kinetics Lipids Magnetic Resonance Spectroscopy Organic chemistry Phosphorylation Phosphotransferases (Alcohol Group Acceptor) - metabolism Preparations and properties Spectrometry, Mass, Electrospray Ionization Sphingosine - analogs & derivatives Sphingosine - chemical synthesis Sphingosine - metabolism
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