Anion-directed synthesis of metal-organic frameworks based on 2-picolinate CuII complexes: a ferromagnetic alternating chain and two unprecedented ferromagnetic fish backbone chains

Three new polynuclear copperII complexes of 2-picolinic acid (Hpic), {[Cu2(pic)3(H2O)]ClO4}n (1), {[Cu2(pic)3(H2O)]BF4}n (2), and [Cu2(pic)3(H2O)2(NO3)]n (3), have been synthesized by reaction of the "metalloligand" [Cu(pic)2] with the corresponding copperII salts. The compounds are charac...

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Veröffentlicht in:	Inorganic chemistry 2007-12, Vol.46 (25), p.10771-10780
Hauptverfasser:	Biswas, Chaitali, Mukherjee, Pampa, Drew, Michael G B, Gómez-García, Carlos J, Clemente-Juan, Juan M, Ghosh, Ashutosh
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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