A Site-Isolated Rhodium−Diethylene Complex Supported on Highly Dealuminated Y Zeolite:  Synthesis and Characterization

The reaction of Rh(C2H4)2(acac) with the partially dehydroxylated surface of dealuminated zeolite Y (calcined at 773 K) and treatments of the resultant surface species in various atmospheres (He, CO, H2, and D2) were investigated with infrared (IR), extended X-ray absorption fine structure (EXAFS),...

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Veröffentlicht in:J. Phys. Chem. B 2005-12, Vol.109 (51), p.24236-24243
Hauptverfasser: Liang, Ann J, Bhirud, Vinesh A, Ehresmann, Justin O, Kletnieks, Philip W, Haw, James F, Gates, Bruce C
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Sprache:eng
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