A kinetic study of lipase-catalyzed reversible kinetic resolution involving verification at miniplant-scale

Lipase‐catalyzed kinetic resolution of racemates is a popular method for synthesis of chiral synthons. Most of these resolutions are reversible equilibrium limited reactions. For the first time, an extensive kinetic model is proposed for kinetic resolution reactions, which takes into account the ful...

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Veröffentlicht in:	Biotechnology and bioengineering 2006-12, Vol.95 (5), p.883-892
Hauptverfasser:	Berendsen, W.R., Gendrot, G., Freund, A., Reuss, M.
Format:	Artikel
Sprache:	eng
Schlagworte:	Biological and medical sciences Biotechnology Candida antarctica Enzymes Enzymes, Immobilized - chemistry Fixed bed reactors Fundamental and applied biological sciences. Psychology kinetic resolution Kinetics lipase Lipase - metabolism miniplant technology modeling and simulation Models, Chemical Parameter estimation Propylene Glycols - isolation & purification Reaction kinetics reversible ping-pong bi-bi mechanism Stereoisomerism Studies Substrates
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