Bi5O7Br and its structural relation to α-Bi5O7I
Pentabismuth heptoxide bromide, Bi5O7Br, crystallizes in the space group Cmca. Its structure is compared with the closely related Ibca structure of α‐Bi5O7I. The change in the space group is assumedly the result of a compromise between the different spatial needs of Br and I and the rigidity of the...
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| Veröffentlicht in: | Acta crystallographica. Section C, Crystal structure communications Crystal structure communications, 2007-12, Vol.63 (12), p.i109-i111 |
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| container_issue | 12 |
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| container_title | Acta crystallographica. Section C, Crystal structure communications |
| container_volume | 63 |
| creator | Keller, E. Krämer, V. |
| description | Pentabismuth heptoxide bromide, Bi5O7Br, crystallizes in the space group Cmca. Its structure is compared with the closely related Ibca structure of α‐Bi5O7I. The change in the space group is assumedly the result of a compromise between the different spatial needs of Br and I and the rigidity of the {3∞}[Bi, O] frameworks into which they are embedded. A detailed procedure for the synthesis of Bi5O7Br is given. |
| doi_str_mv | 10.1107/S0108270107049025 |
| format | Article |
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The change in the space group is assumedly the result of a compromise between the different spatial needs of Br and I and the rigidity of the {3∞}[Bi, O] frameworks into which they are embedded. A detailed procedure for the synthesis of Bi5O7Br is given.</abstract><cop>5 Abbey Square, Chester, Cheshire CH1 2HU, England</cop><pub>Blackwell Publishing Ltd</pub><pmid>18057584</pmid><doi>10.1107/S0108270107049025</doi></addata></record> |
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| ispartof | Acta crystallographica. Section C, Crystal structure communications, 2007-12, Vol.63 (12), p.i109-i111 |
| issn | 0108-2701 1600-5759 |
| language | eng |
| recordid | cdi_proquest_miscellaneous_69015640 |
| source | Wiley Online Library - AutoHoldings Journals; Alma/SFX Local Collection |
| title | Bi5O7Br and its structural relation to α-Bi5O7I |
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