Reversible Concerted Ligand Substitution at Alternating Metal Sites in an Extended Solid
We report a synthetic material, [Co₂(bipy)₃(SO₄)₂(H₂O)₂](bipy) (CH₃OH), (1, where bipy = 4,4'-bipyridyl) that contains discrete reactive and inert structural motifs that undergo a reversible substitution reaction involving the concerted and spatially controlled introduction of bipyridine and me...
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| Veröffentlicht in: | Science (American Association for the Advancement of Science) 2007-02, Vol.315 (5814), p.977-980 |
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| container_title | Science (American Association for the Advancement of Science) |
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| creator | Bradshaw, Darren Warren, John E Rosseinsky, Matthew J |
| description | We report a synthetic material, [Co₂(bipy)₃(SO₄)₂(H₂O)₂](bipy) (CH₃OH), (1, where bipy = 4,4'-bipyridyl) that contains discrete reactive and inert structural motifs that undergo a reversible substitution reaction involving the concerted and spatially controlled introduction of bipyridine and methanol molecules at the reactive sites. This reaction defines the pore geometry of the resulting open-framework structure and controls the manner in which this structure sorbs small molecules. The molecules involved in the reaction are positioned by an array of well-defined interactions during their path to binding to the metal centers. |
| doi_str_mv | 10.1126/science.1135445 |
| format | Article |
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This reaction defines the pore geometry of the resulting open-framework structure and controls the manner in which this structure sorbs small molecules. 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| ispartof | Science (American Association for the Advancement of Science), 2007-02, Vol.315 (5814), p.977-980 |
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| source | JSTOR Archive Collection A-Z Listing; American Association for the Advancement of Science |
| subjects | Analytical chemistry Anions Arrays Atoms Binding Chemistry Colloidal state and disperse state Control equipment Coordination numbers Crystal structure Crystals Exact sciences and technology General and physical chemistry Hydrogen Inert Ligands Metals Methyl alcohol Molecular chains Molecular interactions Molecular structure Molecules Porosity Porous materials Substitution reactions Surface physical chemistry |
| title | Reversible Concerted Ligand Substitution at Alternating Metal Sites in an Extended Solid |
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