Metallanaphthalyne Complex from Zinc Reduction of a Vinylcarbyne Complex

Metallanaphthalyne Complex from Zinc Reduction of a Vinylcarbyne Complex

Cl prevents insertion: The first metallanaphthalyne 2 has been obtained by Zn reduction of Os carbyne complex 1. The key to its isolation was the use of o‐chlorophenyl instead of phenyl substituents to avoid formation of a putative hydrido metallanaphthalyne intermediate (supported by DFT calculatio...

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Veröffentlicht in:Angewandte Chemie (International ed.) 2007-01, Vol.46 (47), p.9065-9068
Hauptverfasser: He, Guomei, Zhu, Jun, Hung, Wai Yiu, Wen, Ting Bin, Sung, Herman Ho-Yung, Williams, Ian Duncan, Lin, Zhenyang, Jia, Guochen
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Sprache:eng
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carbyne ligands
cyclization
indenyl ligands
metallacycles
osmium
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container_end_page 9068
container_issue 47
container_start_page 9065
container_title Angewandte Chemie (International ed.)
container_volume 46
creator He, Guomei
Zhu, Jun
Hung, Wai Yiu
Wen, Ting Bin
Sung, Herman Ho-Yung
Williams, Ian Duncan
Lin, Zhenyang
Jia, Guochen
description Cl prevents insertion: The first metallanaphthalyne 2 has been obtained by Zn reduction of Os carbyne complex 1. The key to its isolation was the use of o‐chlorophenyl instead of phenyl substituents to avoid formation of a putative hydrido metallanaphthalyne intermediate (supported by DFT calculations), which undergoes migratory insertion of the carbyne into the OsH bond and rearrangement to give an indenyl complex as the final product.
doi_str_mv 10.1002/anie.200703289
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subjects carbyne ligands
cyclization
indenyl ligands
metallacycles
osmium
title Metallanaphthalyne Complex from Zinc Reduction of a Vinylcarbyne Complex
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