Tetrahedral nickel nitrosyl complexes with tripodal [N3] and [Se3] donor ancillary ligands: structural and computational evidence that a linear nitrosyl is a trivalent ligand
Linear nickel nitrosyl compounds supported by tridentate nitrogen and selenium ligands, namely the tris(3,5-dimethylpyrazolyl)hydroborato and tris(2-seleno-1-mesitylimidazolyl)hydroborato complexes, [TpMe2]NiNO and [TseMes]NiNO, have been synthesized and structurally characterized by X-ray diffracti...
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| Veröffentlicht in: | Dalton transactions : an international journal of inorganic chemistry 2007-02 (8), p.820-824 |
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| container_title | Dalton transactions : an international journal of inorganic chemistry |
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| creator | Landry, Victoria K Pang, Keliang Quan, Stephanie M Parkin, Gerard |
| description | Linear nickel nitrosyl compounds supported by tridentate nitrogen and selenium ligands, namely the tris(3,5-dimethylpyrazolyl)hydroborato and tris(2-seleno-1-mesitylimidazolyl)hydroborato complexes, [TpMe2]NiNO and [TseMes]NiNO, have been synthesized and structurally characterized by X-ray diffraction. Computational studies demonstrate that the linear nitrosyl ligand behaves as a trivalent X3 ligand such that the Ni-N interaction has multiple bond character. |
| doi_str_mv | 10.1039/b616674a |
| format | Article |
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| ispartof | Dalton transactions : an international journal of inorganic chemistry, 2007-02 (8), p.820-824 |
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| source | MEDLINE; Royal Society Of Chemistry Journals; Royal Society of Chemistry Journals Archive (1841-2007); Alma/SFX Local Collection |
| subjects | Crystallography, X-Ray Ligands Models, Chemical Molecular Structure Nickel - chemistry Organometallic Compounds - chemical synthesis Organometallic Compounds - chemistry Organoselenium Compounds - chemical synthesis Organoselenium Compounds - chemistry |
| title | Tetrahedral nickel nitrosyl complexes with tripodal [N3] and [Se3] donor ancillary ligands: structural and computational evidence that a linear nitrosyl is a trivalent ligand |
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