First Enzymatic Synthesis of Water-Soluble Conducting Poly(3,4-ethylenedioxythiophene)
The enzymatically catalyzed polymerization of 3,4-ethylenedioxythiophene in the presence of polystyrenesulfonate is introduced. This is the first time that an enzymatically catalyzed poly(3,4-ethylenedioxythiophene) (PEDOT) is reported. Horseradish peroxidase enzyme was used as a catalyst for the po...
Gespeichert in:
| Veröffentlicht in: | Biomacromolecules 2007-02, Vol.8 (2), p.315-317 |
|---|---|
| Hauptverfasser: | , , , , , , |
| Format: | Artikel |
| Sprache: | eng |
| Schlagworte: | |
| Online-Zugang: | Volltext |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| container_end_page | 317 |
|---|---|
| container_issue | 2 |
| container_start_page | 315 |
| container_title | Biomacromolecules |
| container_volume | 8 |
| creator | Rumbau, Valérie Pomposo, Jose A Eleta, Aitziber Rodriguez, Javier Grande, Hans Mecerreyes, David Ochoteco, Estibalitz |
| description | The enzymatically catalyzed polymerization of 3,4-ethylenedioxythiophene in the presence of polystyrenesulfonate is introduced. This is the first time that an enzymatically catalyzed poly(3,4-ethylenedioxythiophene) (PEDOT) is reported. Horseradish peroxidase enzyme was used as a catalyst for the polymerization process leading to a water-soluble PEDOT that was characterized by UV−vis spectra, Fourier transform infrared, and electrical conductivity measurements. Water-soluble PEDOT showed excellent film formation ability as confirmed by atomic force microscopy images. |
| doi_str_mv | 10.1021/bm060949z |
| format | Article |
| fullrecord | <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_miscellaneous_68998354</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>68998354</sourcerecordid><originalsourceid>FETCH-LOGICAL-a409t-37fb290f5a0e4bc3cebd477c3eb7d90c0331eb5ed9a8370b7f88ae034c6acb023</originalsourceid><addsrcrecordid>eNpt0MFq3DAQBmARGrrJtoe8QPGlJQtxO7JkyzqWJZsGAglsmxyNJI-7Cra1kWSI8_Rxs0v3ktPMwMc_8BNyRuE7hYz-0B0UILl8OSInNM-KlBeQfXjb81QIKWbkNIRHAJCM5x_JjIpMUsjpCblfWR9ictm_jJ2K1iTrsY8bDDYkrkkeVESfrl076BaTpevrwUTb_03uXDueswueYtyMLfZYW_c8xo112810LT6R40a1AT_v55z8WV3-Xv5Kb26vrpc_b1LFQcaUiUZnEppcAXJtmEFdcyEMQy1qCQYYo6hzrKUqmQAtmrJUCIybQhkNGZuTb7vcrXdPA4ZYdTYYbFvVoxtCVZRSliznE1zsoPEuBI9NtfW2U36sKFT_Sqz-lzjZL_vQQXdYH-S-tQl83QMVjGobr3pjw8GVhQQu5MEpE6pHN_h-6uKdh69GhIal</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>68998354</pqid></control><display><type>article</type><title>First Enzymatic Synthesis of Water-Soluble Conducting Poly(3,4-ethylenedioxythiophene)</title><source>MEDLINE</source><source>American Chemical Society Journals</source><creator>Rumbau, Valérie ; Pomposo, Jose A ; Eleta, Aitziber ; Rodriguez, Javier ; Grande, Hans ; Mecerreyes, David ; Ochoteco, Estibalitz</creator><creatorcontrib>Rumbau, Valérie ; Pomposo, Jose A ; Eleta, Aitziber ; Rodriguez, Javier ; Grande, Hans ; Mecerreyes, David ; Ochoteco, Estibalitz</creatorcontrib><description>The enzymatically catalyzed polymerization of 3,4-ethylenedioxythiophene in the presence of polystyrenesulfonate is introduced. This is the first time that an enzymatically catalyzed poly(3,4-ethylenedioxythiophene) (PEDOT) is reported. Horseradish peroxidase enzyme was used as a catalyst for the polymerization process leading to a water-soluble PEDOT that was characterized by UV−vis spectra, Fourier transform infrared, and electrical conductivity measurements. Water-soluble PEDOT showed excellent film formation ability as confirmed by atomic force microscopy images.</description><identifier>ISSN: 1525-7797</identifier><identifier>EISSN: 1526-4602</identifier><identifier>DOI: 10.1021/bm060949z</identifier><identifier>PMID: 17291051</identifier><language>eng</language><publisher>Washington, DC: American Chemical Society</publisher><subject>Applied sciences ; Bridged Bicyclo Compounds, Heterocyclic - chemical synthesis ; Bridged Bicyclo Compounds, Heterocyclic - chemistry ; Catalysis ; Electric Conductivity ; Exact sciences and technology ; Horseradish Peroxidase - metabolism ; Microscopy, Atomic Force ; Organic polymers ; Physicochemistry of polymers ; Polymers - chemical synthesis ; Polymers - chemistry ; Polymers with particular properties ; Polystyrenes - chemistry ; Preparation, kinetics, thermodynamics, mechanism and catalysts ; Solubility ; Spectrum Analysis ; Water</subject><ispartof>Biomacromolecules, 2007-02, Vol.8 (2), p.315-317</ispartof><rights>Copyright © 2007 American Chemical Society</rights><rights>2007 INIST-CNRS</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-a409t-37fb290f5a0e4bc3cebd477c3eb7d90c0331eb5ed9a8370b7f88ae034c6acb023</citedby><cites>FETCH-LOGICAL-a409t-37fb290f5a0e4bc3cebd477c3eb7d90c0331eb5ed9a8370b7f88ae034c6acb023</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://pubs.acs.org/doi/pdf/10.1021/bm060949z$$EPDF$$P50$$Gacs$$H</linktopdf><linktohtml>$$Uhttps://pubs.acs.org/doi/10.1021/bm060949z$$EHTML$$P50$$Gacs$$H</linktohtml><link.rule.ids>314,780,784,2765,27076,27924,27925,56738,56788</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=18690479$$DView record in Pascal Francis$$Hfree_for_read</backlink><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/17291051$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Rumbau, Valérie</creatorcontrib><creatorcontrib>Pomposo, Jose A</creatorcontrib><creatorcontrib>Eleta, Aitziber</creatorcontrib><creatorcontrib>Rodriguez, Javier</creatorcontrib><creatorcontrib>Grande, Hans</creatorcontrib><creatorcontrib>Mecerreyes, David</creatorcontrib><creatorcontrib>Ochoteco, Estibalitz</creatorcontrib><title>First Enzymatic Synthesis of Water-Soluble Conducting Poly(3,4-ethylenedioxythiophene)</title><title>Biomacromolecules</title><addtitle>Biomacromolecules</addtitle><description>The enzymatically catalyzed polymerization of 3,4-ethylenedioxythiophene in the presence of polystyrenesulfonate is introduced. This is the first time that an enzymatically catalyzed poly(3,4-ethylenedioxythiophene) (PEDOT) is reported. Horseradish peroxidase enzyme was used as a catalyst for the polymerization process leading to a water-soluble PEDOT that was characterized by UV−vis spectra, Fourier transform infrared, and electrical conductivity measurements. Water-soluble PEDOT showed excellent film formation ability as confirmed by atomic force microscopy images.</description><subject>Applied sciences</subject><subject>Bridged Bicyclo Compounds, Heterocyclic - chemical synthesis</subject><subject>Bridged Bicyclo Compounds, Heterocyclic - chemistry</subject><subject>Catalysis</subject><subject>Electric Conductivity</subject><subject>Exact sciences and technology</subject><subject>Horseradish Peroxidase - metabolism</subject><subject>Microscopy, Atomic Force</subject><subject>Organic polymers</subject><subject>Physicochemistry of polymers</subject><subject>Polymers - chemical synthesis</subject><subject>Polymers - chemistry</subject><subject>Polymers with particular properties</subject><subject>Polystyrenes - chemistry</subject><subject>Preparation, kinetics, thermodynamics, mechanism and catalysts</subject><subject>Solubility</subject><subject>Spectrum Analysis</subject><subject>Water</subject><issn>1525-7797</issn><issn>1526-4602</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2007</creationdate><recordtype>article</recordtype><sourceid>EIF</sourceid><recordid>eNpt0MFq3DAQBmARGrrJtoe8QPGlJQtxO7JkyzqWJZsGAglsmxyNJI-7Cra1kWSI8_Rxs0v3ktPMwMc_8BNyRuE7hYz-0B0UILl8OSInNM-KlBeQfXjb81QIKWbkNIRHAJCM5x_JjIpMUsjpCblfWR9ictm_jJ2K1iTrsY8bDDYkrkkeVESfrl076BaTpevrwUTb_03uXDueswueYtyMLfZYW_c8xo112810LT6R40a1AT_v55z8WV3-Xv5Kb26vrpc_b1LFQcaUiUZnEppcAXJtmEFdcyEMQy1qCQYYo6hzrKUqmQAtmrJUCIybQhkNGZuTb7vcrXdPA4ZYdTYYbFvVoxtCVZRSliznE1zsoPEuBI9NtfW2U36sKFT_Sqz-lzjZL_vQQXdYH-S-tQl83QMVjGobr3pjw8GVhQQu5MEpE6pHN_h-6uKdh69GhIal</recordid><startdate>20070201</startdate><enddate>20070201</enddate><creator>Rumbau, Valérie</creator><creator>Pomposo, Jose A</creator><creator>Eleta, Aitziber</creator><creator>Rodriguez, Javier</creator><creator>Grande, Hans</creator><creator>Mecerreyes, David</creator><creator>Ochoteco, Estibalitz</creator><general>American Chemical Society</general><scope>IQODW</scope><scope>CGR</scope><scope>CUY</scope><scope>CVF</scope><scope>ECM</scope><scope>EIF</scope><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7X8</scope></search><sort><creationdate>20070201</creationdate><title>First Enzymatic Synthesis of Water-Soluble Conducting Poly(3,4-ethylenedioxythiophene)</title><author>Rumbau, Valérie ; Pomposo, Jose A ; Eleta, Aitziber ; Rodriguez, Javier ; Grande, Hans ; Mecerreyes, David ; Ochoteco, Estibalitz</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-a409t-37fb290f5a0e4bc3cebd477c3eb7d90c0331eb5ed9a8370b7f88ae034c6acb023</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2007</creationdate><topic>Applied sciences</topic><topic>Bridged Bicyclo Compounds, Heterocyclic - chemical synthesis</topic><topic>Bridged Bicyclo Compounds, Heterocyclic - chemistry</topic><topic>Catalysis</topic><topic>Electric Conductivity</topic><topic>Exact sciences and technology</topic><topic>Horseradish Peroxidase - metabolism</topic><topic>Microscopy, Atomic Force</topic><topic>Organic polymers</topic><topic>Physicochemistry of polymers</topic><topic>Polymers - chemical synthesis</topic><topic>Polymers - chemistry</topic><topic>Polymers with particular properties</topic><topic>Polystyrenes - chemistry</topic><topic>Preparation, kinetics, thermodynamics, mechanism and catalysts</topic><topic>Solubility</topic><topic>Spectrum Analysis</topic><topic>Water</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Rumbau, Valérie</creatorcontrib><creatorcontrib>Pomposo, Jose A</creatorcontrib><creatorcontrib>Eleta, Aitziber</creatorcontrib><creatorcontrib>Rodriguez, Javier</creatorcontrib><creatorcontrib>Grande, Hans</creatorcontrib><creatorcontrib>Mecerreyes, David</creatorcontrib><creatorcontrib>Ochoteco, Estibalitz</creatorcontrib><collection>Pascal-Francis</collection><collection>Medline</collection><collection>MEDLINE</collection><collection>MEDLINE (Ovid)</collection><collection>MEDLINE</collection><collection>MEDLINE</collection><collection>PubMed</collection><collection>CrossRef</collection><collection>MEDLINE - Academic</collection><jtitle>Biomacromolecules</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Rumbau, Valérie</au><au>Pomposo, Jose A</au><au>Eleta, Aitziber</au><au>Rodriguez, Javier</au><au>Grande, Hans</au><au>Mecerreyes, David</au><au>Ochoteco, Estibalitz</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>First Enzymatic Synthesis of Water-Soluble Conducting Poly(3,4-ethylenedioxythiophene)</atitle><jtitle>Biomacromolecules</jtitle><addtitle>Biomacromolecules</addtitle><date>2007-02-01</date><risdate>2007</risdate><volume>8</volume><issue>2</issue><spage>315</spage><epage>317</epage><pages>315-317</pages><issn>1525-7797</issn><eissn>1526-4602</eissn><abstract>The enzymatically catalyzed polymerization of 3,4-ethylenedioxythiophene in the presence of polystyrenesulfonate is introduced. This is the first time that an enzymatically catalyzed poly(3,4-ethylenedioxythiophene) (PEDOT) is reported. Horseradish peroxidase enzyme was used as a catalyst for the polymerization process leading to a water-soluble PEDOT that was characterized by UV−vis spectra, Fourier transform infrared, and electrical conductivity measurements. Water-soluble PEDOT showed excellent film formation ability as confirmed by atomic force microscopy images.</abstract><cop>Washington, DC</cop><pub>American Chemical Society</pub><pmid>17291051</pmid><doi>10.1021/bm060949z</doi><tpages>3</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 1525-7797 |
| ispartof | Biomacromolecules, 2007-02, Vol.8 (2), p.315-317 |
| issn | 1525-7797 1526-4602 |
| language | eng |
| recordid | cdi_proquest_miscellaneous_68998354 |
| source | MEDLINE; American Chemical Society Journals |
| subjects | Applied sciences Bridged Bicyclo Compounds, Heterocyclic - chemical synthesis Bridged Bicyclo Compounds, Heterocyclic - chemistry Catalysis Electric Conductivity Exact sciences and technology Horseradish Peroxidase - metabolism Microscopy, Atomic Force Organic polymers Physicochemistry of polymers Polymers - chemical synthesis Polymers - chemistry Polymers with particular properties Polystyrenes - chemistry Preparation, kinetics, thermodynamics, mechanism and catalysts Solubility Spectrum Analysis Water |
| title | First Enzymatic Synthesis of Water-Soluble Conducting Poly(3,4-ethylenedioxythiophene) |
| url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-01-01T00%3A56%3A28IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=First%20Enzymatic%20Synthesis%20of%20Water-Soluble%20Conducting%20Poly(3,4-ethylenedioxythiophene)&rft.jtitle=Biomacromolecules&rft.au=Rumbau,%20Val%C3%A9rie&rft.date=2007-02-01&rft.volume=8&rft.issue=2&rft.spage=315&rft.epage=317&rft.pages=315-317&rft.issn=1525-7797&rft.eissn=1526-4602&rft_id=info:doi/10.1021/bm060949z&rft_dat=%3Cproquest_cross%3E68998354%3C/proquest_cross%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=68998354&rft_id=info:pmid/17291051&rfr_iscdi=true |