Branch-Selective Intermolecular Hydroacylation: Hydrogen-Mediated Coupling of Anhydrides to Styrenes and Activated Olefins

Branching out with hydrogen: Hydrogenation of symmetric or mixed carboxylic anhydrides in the presence of styrenes or activated olefins generates intermolecular hydroacylation products. The use of cationic rhodium catalysts ligated by triphenylarsine (Ph3As) results in the formation of branched coup...

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Veröffentlicht in:	Angewandte Chemie International Edition 2006-10, Vol.45 (41), p.6885-6888
Hauptverfasser:	Hong, Young-Taek, Barchuk, Andriy, Krische, Michael J.
Format:	Artikel
Sprache:	eng
Schlagworte:	alkenes Alkenes - chemistry Anhydrides - chemistry Catalysis homogeneous catalysis hydroacylation hydrogenation Molecular Structure rhodium Styrenes - chemistry
Online-Zugang:	Volltext
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