Sterically Bulky Tris(triazolyl)borate Ligands as Water-Soluble Analogues of Tris(pyrazolyl)borate
The recently synthesized 3-tert-butyl-5-methyl-1,2,4-triazole reacted with KBH4 to give the new potassium tris(3-tert-butyl-5-methyl-1,2,4-triazolyl)borate K(Ttz t Bu,Me) ligand. Ttz t Bu,Me formed a four-coordinate (Ttz t Bu,Me)CoCl complex and five-coordinate (Ttz t Bu,Me)CoNO3 and (Ttz t Bu,Me)Zn...
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| Veröffentlicht in: | Inorganic chemistry 2007-01, Vol.46 (2), p.360-362 |
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| container_title | Inorganic chemistry |
| container_volume | 46 |
| creator | Jernigan, Finith E. Sieracki, Nathan A. Taylor, Michael T. Jenkins, Aaron S. Engel, Sharon E. Rowe, Brittany W. Jové, Fernando A. Yap, Glenn P. A. Papish, Elizabeth T. Ferrence, Gregory M. |
| description | The recently synthesized 3-tert-butyl-5-methyl-1,2,4-triazole reacted with KBH4 to give the new potassium tris(3-tert-butyl-5-methyl-1,2,4-triazolyl)borate K(Ttz t Bu,Me) ligand. Ttz t Bu,Me formed a four-coordinate (Ttz t Bu,Me)CoCl complex and five-coordinate (Ttz t Bu,Me)CoNO3 and (Ttz t Bu,Me)ZnOAc complexes. When these complexes were compared to their Tp t Bu,Me analogues, it was found that Ttz t Bu,Me resulted in negligible steric differences. K(Ttz t Bu,Me) is more water-soluble than K(Tp t Bu,Me), so bulky tris(triazolyl)borate ligands should lead to functional models for enzyme active sites in an aqueous environment and the creation of water-soluble analogues of Tp catalysts. |
| doi_str_mv | 10.1021/ic061828a |
| format | Article |
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Chem</addtitle><date>2007-01-22</date><risdate>2007</risdate><volume>46</volume><issue>2</issue><spage>360</spage><epage>362</epage><pages>360-362</pages><issn>0020-1669</issn><eissn>1520-510X</eissn><abstract>The recently synthesized 3-tert-butyl-5-methyl-1,2,4-triazole reacted with KBH4 to give the new potassium tris(3-tert-butyl-5-methyl-1,2,4-triazolyl)borate K(Ttz t Bu,Me) ligand. Ttz t Bu,Me formed a four-coordinate (Ttz t Bu,Me)CoCl complex and five-coordinate (Ttz t Bu,Me)CoNO3 and (Ttz t Bu,Me)ZnOAc complexes. When these complexes were compared to their Tp t Bu,Me analogues, it was found that Ttz t Bu,Me resulted in negligible steric differences. K(Ttz t Bu,Me) is more water-soluble than K(Tp t Bu,Me), so bulky tris(triazolyl)borate ligands should lead to functional models for enzyme active sites in an aqueous environment and the creation of water-soluble analogues of Tp catalysts.</abstract><cop>United States</cop><pub>American Chemical Society</pub><pmid>17279808</pmid><doi>10.1021/ic061828a</doi><tpages>3</tpages></addata></record> |
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| title | Sterically Bulky Tris(triazolyl)borate Ligands as Water-Soluble Analogues of Tris(pyrazolyl)borate |
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