A Square-Planar Organoiron(III) Compound with a Spin-Admixed State
Square‐planar iron(III) species bearing no axial ligands can still behave as spin‐admixed systems (S=3/2, 5/2). The highly unusual homoleptic σ‐organoiron complex [Li(thf)4][FeIII(C6Cl5)4] (see anion in picture; green Cl, gray C) is an example of such a system.
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| Veröffentlicht in: | Angewandte Chemie International Edition 2006-10, Vol.45 (40), p.6707-6711 |
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| container_title | Angewandte Chemie International Edition |
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| creator | Alonso, Pablo J. Arauzo, Ana B. Forniés, Juan García-Monforte, M. Angeles Martín, Antonio Martínez, Jesús I. Menjón, Babil Rillo, Conrado Sáiz-Garitaonandia, José J. |
| description | Square‐planar iron(III) species bearing no axial ligands can still behave as spin‐admixed systems (S=3/2, 5/2). The highly unusual homoleptic σ‐organoiron complex [Li(thf)4][FeIII(C6Cl5)4] (see anion in picture; green Cl, gray C) is an example of such a system. |
| doi_str_mv | 10.1002/anie.200601774 |
| format | Article |
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The highly unusual homoleptic σ‐organoiron complex [Li(thf)4][FeIII(C6Cl5)4] (see anion in picture; green Cl, gray C) is an example of such a system.</abstract><cop>Weinheim</cop><pub>WILEY-VCH Verlag</pub><pmid>16977656</pmid><doi>10.1002/anie.200601774</doi><tpages>5</tpages></addata></record> |
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| language | eng |
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| source | MEDLINE; Wiley Online Library Journals Frontfile Complete |
| subjects | Chemistry, Organic Electron Spin Resonance Spectroscopy EPR spectroscopy homoleptic compounds iron Iron - chemistry Lithium - chemistry magnetic properties Models, Chemical Moessbauer spectroscopy Molecular Structure Organic Chemistry Phenomena Organometallic Compounds - chemistry Oxidation-Reduction |
| title | A Square-Planar Organoiron(III) Compound with a Spin-Admixed State |
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