Electronic Structure and Stability of Pentaorganosilicates

The exceptional stability of recently reported pentaorganosilicates is investigated by bond energy analyses. Experimental coupling constants are used to probe their electronic structure, entailing bonds with mixed ionic−covalent character. Our analyses reconfirm that the axial bonds are more prone t...

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Veröffentlicht in:	Journal of the American Chemical Society 2006-10, Vol.128 (41), p.13634-13639
Hauptverfasser:	Couzijn, Erik P. A, Ehlers, Andreas W, Schakel, Marius, Lammertsma, Koop
Format:	Artikel
Sprache:	eng
Schlagworte:	Chemistry Exact sciences and technology General and physical chemistry Noncondensed benzenic compounds Organic chemistry Preparations and properties
Online-Zugang:	Volltext
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