Circular Dichroism Laser Mass Spectrometry: Differentiation of 3-Methylcyclopentanone Enantiomers
Rotational sense does matter! Left and right circularly polarised laser light can be used to achieve different ionisation yields when applying multiphoton ionisation to chiral ketones (see picture). So a new type of enantioselective laser mass spectrometry becomes possible which also gives informati...
Gespeichert in:
| Veröffentlicht in: | Chemphyschem 2006-10, Vol.7 (10), p.2085-2087 |
|---|---|
| Hauptverfasser: | , |
| Format: | Artikel |
| Sprache: | eng |
| Schlagworte: | |
| Online-Zugang: | Volltext |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| container_end_page | 2087 |
|---|---|
| container_issue | 10 |
| container_start_page | 2085 |
| container_title | Chemphyschem |
| container_volume | 7 |
| creator | Boesl von Grafenstein, Ulrich Bornschlegl, Alexander |
| description | Rotational sense does matter! Left and right circularly polarised laser light can be used to achieve different ionisation yields when applying multiphoton ionisation to chiral ketones (see picture). So a new type of enantioselective laser mass spectrometry becomes possible which also gives information on the involved electronic transitions. |
| doi_str_mv | 10.1002/cphc.200600376 |
| format | Article |
| fullrecord | <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_miscellaneous_68943786</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>68943786</sourcerecordid><originalsourceid>FETCH-LOGICAL-c3266-614c981a992bfbb7c9808ebfb2ecb00a0e6ef6fbb49d8c679d685a90fa5614123</originalsourceid><addsrcrecordid>eNqFkE1v1DAQhi0EoqVw5YhygVsWfySOzQ2FskXaFiRAHK2Jd6w1JHFqZwX597jaqOXGaWY0zzO2XkJeMrphlPK3djrYDadUUioa-Yics0rospEVe7z2FRf1GXmW0k9KqaINe0rOmNQVq2t5TqD10R57iMUHbw8x-DQUO0gYi2tIqfg6oZ1jGHCOy7uMOIcRx9nD7MNYBFeI8hrnw9LbxfZhyisYw4jF5QiZyl5Mz8kTB33CF2u9IN8_Xn5rr8rd5-2n9v2utIJLWUpWWa0YaM0713VNHqjC3HK0HaVAUaKTeVPpvbKy0XupatDUQZ1VxsUFeXO6O8Vwe8Q0m8Eni30PI4ZjMlLpSjRKZnBzAm0MKUV0Zop-gLgYRs1dqOYuVHMfahZerZeP3YD7B3xNMQOvVwCShd5FGK1PD5xiSmquM6dP3G_f4_KfZ0375ar99xPlyfVpxj_3LsRfRjaiqc2Pm63hYntTV5waLf4CSBGg_A</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>68943786</pqid></control><display><type>article</type><title>Circular Dichroism Laser Mass Spectrometry: Differentiation of 3-Methylcyclopentanone Enantiomers</title><source>MEDLINE</source><source>Wiley Online Library All Journals</source><creator>Boesl von Grafenstein, Ulrich ; Bornschlegl, Alexander</creator><creatorcontrib>Boesl von Grafenstein, Ulrich ; Bornschlegl, Alexander</creatorcontrib><description>Rotational sense does matter! Left and right circularly polarised laser light can be used to achieve different ionisation yields when applying multiphoton ionisation to chiral ketones (see picture). So a new type of enantioselective laser mass spectrometry becomes possible which also gives information on the involved electronic transitions.</description><identifier>ISSN: 1439-4235</identifier><identifier>EISSN: 1439-7641</identifier><identifier>DOI: 10.1002/cphc.200600376</identifier><identifier>PMID: 16941556</identifier><language>eng</language><publisher>Weinheim: WILEY-VCH Verlag</publisher><subject>Analytical chemistry ; Calibration ; carbonyl compounds ; Chemistry ; chirality ; circular dichroism ; Circular Dichroism - instrumentation ; Circular Dichroism - methods ; Cyclopentanes - chemistry ; Exact sciences and technology ; laser spectroscopy ; mass spectrometry ; Spectrometric and optical methods ; Spectrometry, Mass, Matrix-Assisted Laser Desorption-Ionization - instrumentation ; Spectrometry, Mass, Matrix-Assisted Laser Desorption-Ionization - methods ; Stereoisomerism</subject><ispartof>Chemphyschem, 2006-10, Vol.7 (10), p.2085-2087</ispartof><rights>Copyright © 2006 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim</rights><rights>2007 INIST-CNRS</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c3266-614c981a992bfbb7c9808ebfb2ecb00a0e6ef6fbb49d8c679d685a90fa5614123</citedby><cites>FETCH-LOGICAL-c3266-614c981a992bfbb7c9808ebfb2ecb00a0e6ef6fbb49d8c679d685a90fa5614123</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://onlinelibrary.wiley.com/doi/pdf/10.1002%2Fcphc.200600376$$EPDF$$P50$$Gwiley$$H</linktopdf><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1002%2Fcphc.200600376$$EHTML$$P50$$Gwiley$$H</linktohtml><link.rule.ids>314,780,784,1417,27924,27925,45574,45575</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=18186929$$DView record in Pascal Francis$$Hfree_for_read</backlink><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/16941556$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Boesl von Grafenstein, Ulrich</creatorcontrib><creatorcontrib>Bornschlegl, Alexander</creatorcontrib><title>Circular Dichroism Laser Mass Spectrometry: Differentiation of 3-Methylcyclopentanone Enantiomers</title><title>Chemphyschem</title><addtitle>ChemPhysChem</addtitle><description>Rotational sense does matter! Left and right circularly polarised laser light can be used to achieve different ionisation yields when applying multiphoton ionisation to chiral ketones (see picture). So a new type of enantioselective laser mass spectrometry becomes possible which also gives information on the involved electronic transitions.</description><subject>Analytical chemistry</subject><subject>Calibration</subject><subject>carbonyl compounds</subject><subject>Chemistry</subject><subject>chirality</subject><subject>circular dichroism</subject><subject>Circular Dichroism - instrumentation</subject><subject>Circular Dichroism - methods</subject><subject>Cyclopentanes - chemistry</subject><subject>Exact sciences and technology</subject><subject>laser spectroscopy</subject><subject>mass spectrometry</subject><subject>Spectrometric and optical methods</subject><subject>Spectrometry, Mass, Matrix-Assisted Laser Desorption-Ionization - instrumentation</subject><subject>Spectrometry, Mass, Matrix-Assisted Laser Desorption-Ionization - methods</subject><subject>Stereoisomerism</subject><issn>1439-4235</issn><issn>1439-7641</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2006</creationdate><recordtype>article</recordtype><sourceid>EIF</sourceid><recordid>eNqFkE1v1DAQhi0EoqVw5YhygVsWfySOzQ2FskXaFiRAHK2Jd6w1JHFqZwX597jaqOXGaWY0zzO2XkJeMrphlPK3djrYDadUUioa-Yics0rospEVe7z2FRf1GXmW0k9KqaINe0rOmNQVq2t5TqD10R57iMUHbw8x-DQUO0gYi2tIqfg6oZ1jGHCOy7uMOIcRx9nD7MNYBFeI8hrnw9LbxfZhyisYw4jF5QiZyl5Mz8kTB33CF2u9IN8_Xn5rr8rd5-2n9v2utIJLWUpWWa0YaM0713VNHqjC3HK0HaVAUaKTeVPpvbKy0XupatDUQZ1VxsUFeXO6O8Vwe8Q0m8Eni30PI4ZjMlLpSjRKZnBzAm0MKUV0Zop-gLgYRs1dqOYuVHMfahZerZeP3YD7B3xNMQOvVwCShd5FGK1PD5xiSmquM6dP3G_f4_KfZ0375ar99xPlyfVpxj_3LsRfRjaiqc2Pm63hYntTV5waLf4CSBGg_A</recordid><startdate>20061013</startdate><enddate>20061013</enddate><creator>Boesl von Grafenstein, Ulrich</creator><creator>Bornschlegl, Alexander</creator><general>WILEY-VCH Verlag</general><general>WILEY‐VCH Verlag</general><general>Wiley</general><scope>BSCLL</scope><scope>IQODW</scope><scope>CGR</scope><scope>CUY</scope><scope>CVF</scope><scope>ECM</scope><scope>EIF</scope><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7X8</scope></search><sort><creationdate>20061013</creationdate><title>Circular Dichroism Laser Mass Spectrometry: Differentiation of 3-Methylcyclopentanone Enantiomers</title><author>Boesl von Grafenstein, Ulrich ; Bornschlegl, Alexander</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c3266-614c981a992bfbb7c9808ebfb2ecb00a0e6ef6fbb49d8c679d685a90fa5614123</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2006</creationdate><topic>Analytical chemistry</topic><topic>Calibration</topic><topic>carbonyl compounds</topic><topic>Chemistry</topic><topic>chirality</topic><topic>circular dichroism</topic><topic>Circular Dichroism - instrumentation</topic><topic>Circular Dichroism - methods</topic><topic>Cyclopentanes - chemistry</topic><topic>Exact sciences and technology</topic><topic>laser spectroscopy</topic><topic>mass spectrometry</topic><topic>Spectrometric and optical methods</topic><topic>Spectrometry, Mass, Matrix-Assisted Laser Desorption-Ionization - instrumentation</topic><topic>Spectrometry, Mass, Matrix-Assisted Laser Desorption-Ionization - methods</topic><topic>Stereoisomerism</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Boesl von Grafenstein, Ulrich</creatorcontrib><creatorcontrib>Bornschlegl, Alexander</creatorcontrib><collection>Istex</collection><collection>Pascal-Francis</collection><collection>Medline</collection><collection>MEDLINE</collection><collection>MEDLINE (Ovid)</collection><collection>MEDLINE</collection><collection>MEDLINE</collection><collection>PubMed</collection><collection>CrossRef</collection><collection>MEDLINE - Academic</collection><jtitle>Chemphyschem</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Boesl von Grafenstein, Ulrich</au><au>Bornschlegl, Alexander</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Circular Dichroism Laser Mass Spectrometry: Differentiation of 3-Methylcyclopentanone Enantiomers</atitle><jtitle>Chemphyschem</jtitle><addtitle>ChemPhysChem</addtitle><date>2006-10-13</date><risdate>2006</risdate><volume>7</volume><issue>10</issue><spage>2085</spage><epage>2087</epage><pages>2085-2087</pages><issn>1439-4235</issn><eissn>1439-7641</eissn><abstract>Rotational sense does matter! Left and right circularly polarised laser light can be used to achieve different ionisation yields when applying multiphoton ionisation to chiral ketones (see picture). So a new type of enantioselective laser mass spectrometry becomes possible which also gives information on the involved electronic transitions.</abstract><cop>Weinheim</cop><pub>WILEY-VCH Verlag</pub><pmid>16941556</pmid><doi>10.1002/cphc.200600376</doi><tpages>3</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 1439-4235 |
| ispartof | Chemphyschem, 2006-10, Vol.7 (10), p.2085-2087 |
| issn | 1439-4235 1439-7641 |
| language | eng |
| recordid | cdi_proquest_miscellaneous_68943786 |
| source | MEDLINE; Wiley Online Library All Journals |
| subjects | Analytical chemistry Calibration carbonyl compounds Chemistry chirality circular dichroism Circular Dichroism - instrumentation Circular Dichroism - methods Cyclopentanes - chemistry Exact sciences and technology laser spectroscopy mass spectrometry Spectrometric and optical methods Spectrometry, Mass, Matrix-Assisted Laser Desorption-Ionization - instrumentation Spectrometry, Mass, Matrix-Assisted Laser Desorption-Ionization - methods Stereoisomerism |
| title | Circular Dichroism Laser Mass Spectrometry: Differentiation of 3-Methylcyclopentanone Enantiomers |
| url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-01-07T22%3A10%3A35IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Circular%20Dichroism%20Laser%20Mass%20Spectrometry:%20Differentiation%20of%203-Methylcyclopentanone%20Enantiomers&rft.jtitle=Chemphyschem&rft.au=Boesl%20von%20Grafenstein,%20Ulrich&rft.date=2006-10-13&rft.volume=7&rft.issue=10&rft.spage=2085&rft.epage=2087&rft.pages=2085-2087&rft.issn=1439-4235&rft.eissn=1439-7641&rft_id=info:doi/10.1002/cphc.200600376&rft_dat=%3Cproquest_cross%3E68943786%3C/proquest_cross%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=68943786&rft_id=info:pmid/16941556&rfr_iscdi=true |