Ligand-Controlled, Complementary Stereoselectivity in the Platinum-Catalyzed Intramolecular Silaboration of Alkenes

An intramolecular silaboration of borylsilanyl homoallyl ethers was achieved using a platinum catalyst, giving 1-oxa-2-silacyclopentanes in high yields. The stereoselectivity of the reactions of sec-homoallyl ethers strongly depended on the phosphorus ligand of the platinum catalysts used. The plati...

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Veröffentlicht in:	Journal of the American Chemical Society 2006-10, Vol.128 (41), p.13366-13367
Hauptverfasser:	Ohmura, Toshimichi, Furukawa, Hideki, Suginome, Michinori
Format:	Artikel
Sprache:	eng
Schlagworte:	Chemistry Exact sciences and technology General and physical chemistry
Online-Zugang:	Volltext
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