Sequential multiphoton absorption enhancement induced by zinc complexation in functionalized distyrylbenzene analogs

Functionalized distyrylbenzene analogs and , bearing a tris-(2-pyridylmethyl)amine-based receptor for Zn(2+), were synthesized by a Horner-Emmons-Wittig coupling reaction. It has been found that Zn(2+) complexation induces changes in the linear absorption spectrum that enhance a nonlinear sequential...

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Veröffentlicht in:Physical chemistry chemical physics : PCCP 2007-01, Vol.9 (5), p.616-621
Hauptverfasser: FABBRINI, Graziano, RICCO, Raffaele, MENNA, Enzo, MAGGINI, Michele, AMENDOLA, Vincenzo, GARBIN, Mattia, VILLANO, Massimo, MENEGHETTI, Moreno
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container_issue 5
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container_title Physical chemistry chemical physics : PCCP
container_volume 9
creator FABBRINI, Graziano
RICCO, Raffaele
MENNA, Enzo
MAGGINI, Michele
AMENDOLA, Vincenzo
GARBIN, Mattia
VILLANO, Massimo
MENEGHETTI, Moreno
description Functionalized distyrylbenzene analogs and , bearing a tris-(2-pyridylmethyl)amine-based receptor for Zn(2+), were synthesized by a Horner-Emmons-Wittig coupling reaction. It has been found that Zn(2+) complexation induces changes in the linear absorption spectrum that enhance a nonlinear sequential two-photon absorption of nanosecond pulses at 532 nm. This absorption was also found to depend on the nature of the substituent at the side benzene ring of the styrylbenzene structure.
doi_str_mv 10.1039/b615076d
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source Royal Society of Chemistry Journals Archive (1841-2007); MEDLINE; Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection
subjects Benzene Derivatives - chemical synthesis
Benzene Derivatives - chemistry
Chemistry
Exact sciences and technology
General and physical chemistry
Molecular Structure
Organometallic Compounds - chemistry
Photons
Styrenes - chemistry
Zinc - chemistry
title Sequential multiphoton absorption enhancement induced by zinc complexation in functionalized distyrylbenzene analogs
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