Vibrational Relaxation of CN Stretch of Pseudo-Halide Anions (OCN-, SCN-, and SeCN-) in Polar Solvents

The vibrational relaxation dynamics of pseudo-halide anions XCN- (X=O, S, Se) in polar solvents were studied to understand the effect of charge on solute-to-solvent intermolecular energy transfer (IET) and solvent assisted intramolecular vibrational relaxation (IVR) pathways. The T 1 relaxation time...

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Veröffentlicht in:	The journal of physical chemistry. B 2006-10, Vol.110 (40), p.19990-19997
Hauptverfasser:	Lenchenkov, Victor, She, Chunxing, Lian, Tianquan
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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