Ultrafast and Ultraslow Oxygen Atom Transfer Reactions between Late Metal Centers

Oxotrimesityliridium(V), (mes)3IrO (mes = 2,4,6-trimethylphenyl), and trimesityliridium(III), (mes)3Ir, undergo extremely rapid degenerate intermetal oxygen atom transfer at room temperature. At low temperatures, the two complexes conproportionate to form (mes)3IrOIr(mes)3, the 2,6-dimethylphenyl...

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Veröffentlicht in:	Journal of the American Chemical Society 2007-01, Vol.129 (3), p.588-600
Hauptverfasser:	Fortner, Kevin C, Laitar, David S, Muldoon, John, Pu, Lihung, Braun-Sand, Sonja B, Wiest, Olaf, Brown, Seth N
Format:	Artikel
Sprache:	eng
Schlagworte:	Cold Temperature Iridium - chemistry Kinetics Magnetic Resonance Spectroscopy Metals - chemistry Organometallic Compounds - chemistry Osmium - chemistry Oxidation-Reduction Oxygen - chemistry
Online-Zugang:	Volltext
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