From Controllable Attached Isolation Moieties to Possibly Highly Efficient Nonlinear Optical Main-Chain Polyurethanes Containing Indole-Based Chromophores
For the first time, the indole-based NLO chromophores were embedded into the polymer main chain, and different isolation groups were attached to their donor side with the efforts of adjusting the NLO properties of the resultant main-chain polyurethanes, according to the site isolation principle. Tha...
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| Veröffentlicht in: | The journal of physical chemistry. B 2007-01, Vol.111 (3), p.508-514 |
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| container_end_page | 514 |
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| container_issue | 3 |
| container_start_page | 508 |
| container_title | The journal of physical chemistry. B |
| container_volume | 111 |
| creator | Li, Qianqian Li, Zhen Zeng, Fanxin Gong, Wei Li, Zhong'an Zhu, Zhichao Zeng, Qi Yu, Shanshan Ye, Cheng Qin, Jingui |
| description | For the first time, the indole-based NLO chromophores were embedded into the polymer main chain, and different isolation groups were attached to their donor side with the efforts of adjusting the NLO properties of the resultant main-chain polyurethanes, according to the site isolation principle. Thanks to the main-chain structure and the advantages of the indole-based chromophores, all the polymers show excellent transparency, good processability, thermal stability, and relatively good NLO effects. The tested NLO properties of the polymers demonstrate that there is a suitable isolation group present for the sulfonyl-based chromophore to boost its microscopic β value to a possibly higher macroscopic NLO property efficiently. |
| doi_str_mv | 10.1021/jp066489l |
| format | Article |
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| ispartof | The journal of physical chemistry. B, 2007-01, Vol.111 (3), p.508-514 |
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| language | eng |
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| source | ACS Publications |
| title | From Controllable Attached Isolation Moieties to Possibly Highly Efficient Nonlinear Optical Main-Chain Polyurethanes Containing Indole-Based Chromophores |
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