Diastereomerically-Specific Zirconium Complexes of Chiral Salan Ligands:  Isospecific Polymerization of 1-Hexene and 4-Methyl-1-pentene and Cyclopolymerization of 1,5-Hexadiene

Chiral Salan ligands were found to wrap in a highly diastereoselective manner around zirconium leading to C 2-symmetric complexes of predetermined chirality at the metal. These complexes led to active polymerization of higher olefins, their activity and isospecific induction depending on the nature...

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Veröffentlicht in:Journal of the American Chemical Society 2006-10, Vol.128 (40), p.13062-13063
Hauptverfasser: Yeori, Adi, Goldberg, Israel, Shuster, Michael, Kol, Moshe
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Sprache:eng
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