Diastereomerically-Specific Zirconium Complexes of Chiral Salan Ligands: Isospecific Polymerization of 1-Hexene and 4-Methyl-1-pentene and Cyclopolymerization of 1,5-Hexadiene
Chiral Salan ligands were found to wrap in a highly diastereoselective manner around zirconium leading to C 2-symmetric complexes of predetermined chirality at the metal. These complexes led to active polymerization of higher olefins, their activity and isospecific induction depending on the nature...
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Veröffentlicht in: | Journal of the American Chemical Society 2006-10, Vol.128 (40), p.13062-13063 |
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