$X-ray Diffraction and EXAFS Studies of Hydroxo−Cu(II) Complexes Based on a Calix[6]arene-N3 Ligand: Evidence for a Mononuclear−Dinuclear Equilibrium Controlled by Supramolecular Features$

X-ray Diffraction and EXAFS Studies of Hydroxo−Cu(II) Complexes Based on a Calix[6]arene-N3 Ligand: Evidence for a Mononuclear−Dinuclear Equilibrium Controlled by Supramolecular Features

The formation of hydroxo complexes based on a calix[6]trisimidazole ligand is described. Deprotonation of the mononuclear Cu(II)−aqua complex gives rise to a dinuclear bis(μ-hydroxo) complex that has been characterized by X-ray diffraction analysis. Spectroscopic studies (EPR and UV−vis), conducted...

Ausführliche Beschreibung

Gespeichert in:

Bibliographische Detailangaben
Veröffentlicht in:	Inorganic chemistry 2005-12, Vol.44 (26), p.9743-9751
Hauptverfasser:	Izzet, Guillaume, Frapart, Yves M, Prangé, Thierry, Provost, Karine, Michalowicz, Alain, Reinaud, Olivia
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
Tags:	Tag hinzufügen Keine Tags, Fügen Sie den ersten Tag hinzu!

Schreiben Sie den ersten Kommentar!