2,2'-Disubstituted F12binaphthyl derivatives: stannanes, boranes, and (R)-F12BINOL
2,2'-Distannyl derivatives of dodecafluorobinaphthalene are converted to a novel D2 symmetric borane dimer, which can be oxidized to (+)-F12BINOL; resolution using (S)-acetoxypropanoyl chloride affords enantiopure material.
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Veröffentlicht in: | Chemical communications (Cambridge, England) England), 2006-07 (27), p.2875-2877 |
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container_title | Chemical communications (Cambridge, England) |
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creator | Morrison, Darryl J Riegel, Susanne D Piers, Warren E Parvez, Masood McDonald, Robert |
description | 2,2'-Distannyl derivatives of dodecafluorobinaphthalene are converted to a novel D2 symmetric borane dimer, which can be oxidized to (+)-F12BINOL; resolution using (S)-acetoxypropanoyl chloride affords enantiopure material. |
doi_str_mv | 10.1039/b605716k |
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source | Royal Society of Chemistry Journals Archive (1841-2007); Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection |
title | 2,2'-Disubstituted F12binaphthyl derivatives: stannanes, boranes, and (R)-F12BINOL |
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