C-H activation of alkanes on Rh+ n (n=1-30) clusters: size effects on dehydrogenation

The rate coefficients for the dehydrogenation of ethane, propane, and isobutane with cationic rhodium atoms Rh+ and clusters Rh+ n of up to 30 atoms were measured under single-collision conditions in a Fourier-transform ion cyclotron resonance mass spectrometer. The reaction rates are cluster size d...

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Veröffentlicht in:	The Journal of chemical physics 2005-12, Vol.123 (21), p.214709-214709
Hauptverfasser:	Adlhart, Christian, Uggerud, Einar
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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