Synthesis and Structural Characterization of Neutral Higher-Coordinate Silicon(iv) Complexes with Tridentate Dianionic Chelate Ligands

The neutral pentacoordinate silicon(iv) complexes 8 and 9 with an SiO2N3 skeleton and the neutral hexacoordinate silicon(iv) complex 10⋅ 1/2 CH3CN with an SiO4N2 skeleton were synthesized, starting from tetra(cyanato‐N)silane or tetra(thiocyanato‐N)silane. Compounds 8 and 9 contain one tridentate di...

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Veröffentlicht in:	Chemistry : a European journal 2005-12, Vol.11 (24), p.7379-7386
Hauptverfasser:	Seiler, Oliver, Burschka, Christian, Metz, Stefan, Penka, Martin, Tacke, Reinhold
Format:	Artikel
Sprache:	eng
Schlagworte:	coordination chemistry cyanato-N ligands silicon thiocyanato-N ligands tridentate ligands
Online-Zugang:	Volltext
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