Molecular Dynamics Simulations of Alkylsilane Stationary-Phase Order and Disorder. 1. Effects of Surface Coverage and Bonding Chemistry

“Shape-selective” polymeric alkylsilane stationary phases are routinely employed over the more common monomeric phases in reversed-phase liquid chromatography (RPLC) to improve the separation of geometric isomers of shape-constrained solutes. We have investigated the molecular dynamics of chromatogr...

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Veröffentlicht in:	Analytical chemistry (Washington) 2005-12, Vol.77 (24), p.7852-7861
Hauptverfasser:	Lippa, Katrice A, Sander, Lane C, Mountain, Raymond D
Format:	Artikel
Sprache:	eng
Schlagworte:	Analytical chemistry Chemical bonds Chemistry Chromatographic methods and physical methods associated with chromatography Chromatography Exact sciences and technology Molecular structure Other chromatographic methods Polymers Solid solutions
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