N-Acylureido Functionality as Acceptor Substituent in Solvatochromic Fluorescence Probes:  Detection of Carboxylic Acids, Alcohols, and Fluoride Ions

N-Acylureido Functionality as Acceptor Substituent in Solvatochromic Fluorescence Probes:  Detection of Carboxylic Acids, Alcohols, and Fluoride Ions

N,N‘-Dicyclohexyl-N-(6‘-methoxyanthryl-2-carbonyl)urea (1a) exhibits a strong solvatochromism with respect to its fluorescence properties. The emission maxima of 1a correlate well with the anion-stabilizing properties of the solvent. This feature allows the detection of analytes with high acceptor n...

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Veröffentlicht in:Journal of the American Chemical Society 2005-12, Vol.127 (49), p.17158-17159
Hauptverfasser: Bohne, Cornelia, Ihmels, Heiko, Waidelich, Michael, Yihwa, Chang
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Analytical chemistry
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General, instrumentation
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container_issue 49
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container_title Journal of the American Chemical Society
container_volume 127
creator Bohne, Cornelia
Ihmels, Heiko
Waidelich, Michael
Yihwa, Chang
description N,N‘-Dicyclohexyl-N-(6‘-methoxyanthryl-2-carbonyl)urea (1a) exhibits a strong solvatochromism with respect to its fluorescence properties. The emission maxima of 1a correlate well with the anion-stabilizing properties of the solvent. This feature allows the detection of analytes with high acceptor numbers, such as alcohols and carboxylic acids, and the detection of analytes such as fluoride ions which form strong hydrogen bonds with the amido hydrogen atom.
doi_str_mv 10.1021/ja052262c
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subjects Analytical chemistry
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General, instrumentation
title N-Acylureido Functionality as Acceptor Substituent in Solvatochromic Fluorescence Probes:  Detection of Carboxylic Acids, Alcohols, and Fluoride Ions
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