Cobalt-Catalyzed Dimerization of α-Olefins to Give Linear α-Olefin Products
[Cp*P(OMe)3CoCH2CH3]+ [BarF]-, generated by the addition of HBArF to Cp*P(OMe)3Co(ethene), catalyzes the oligomerization of 1-hexene to give dimers and trimers. When a deficit of the acid is used, linear α-olefin dimers are produced at the expense of trimeric products: e.g., 1-butene, 1-hexene, and...
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| Veröffentlicht in: | Journal of the American Chemical Society 2005-12, Vol.127 (49), p.17194-17195 |
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| container_end_page | 17195 |
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| container_issue | 49 |
| container_start_page | 17194 |
| container_title | Journal of the American Chemical Society |
| container_volume | 127 |
| creator | Broene, Richard D Brookhart, Maurice Lamanna, William M Volpe, Anthony F |
| description | [Cp*P(OMe)3CoCH2CH3]+ [BarF]-, generated by the addition of HBArF to Cp*P(OMe)3Co(ethene), catalyzes the oligomerization of 1-hexene to give dimers and trimers. When a deficit of the acid is used, linear α-olefin dimers are produced at the expense of trimeric products: e.g., 1-butene, 1-hexene, and 1-octene give 1-octene, 1-dodecene, and 1-hexadecene, respectively. |
| doi_str_mv | 10.1021/ja056655n |
| format | Article |
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When a deficit of the acid is used, linear α-olefin dimers are produced at the expense of trimeric products: e.g., 1-butene, 1-hexene, and 1-octene give 1-octene, 1-dodecene, and 1-hexadecene, respectively.</description><identifier>ISSN: 0002-7863</identifier><identifier>EISSN: 1520-5126</identifier><identifier>DOI: 10.1021/ja056655n</identifier><identifier>PMID: 16332061</identifier><identifier>CODEN: JACSAT</identifier><language>eng</language><publisher>Washington, DC: American Chemical Society</publisher><subject>Chemistry ; Exact sciences and technology ; Kinetics and mechanisms ; Organic chemistry ; Reactivity and mechanisms</subject><ispartof>Journal of the American Chemical Society, 2005-12, Vol.127 (49), p.17194-17195</ispartof><rights>Copyright © 2005 American Chemical Society</rights><rights>2006 INIST-CNRS</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-a381t-8001a16c06e527c130a710182754588c772a10ea62e6ae9ea29895f85ed86ad13</citedby><cites>FETCH-LOGICAL-a381t-8001a16c06e527c130a710182754588c772a10ea62e6ae9ea29895f85ed86ad13</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://pubs.acs.org/doi/pdf/10.1021/ja056655n$$EPDF$$P50$$Gacs$$H</linktopdf><linktohtml>$$Uhttps://pubs.acs.org/doi/10.1021/ja056655n$$EHTML$$P50$$Gacs$$H</linktohtml><link.rule.ids>314,776,780,2752,27053,27901,27902,56713,56763</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=17371307$$DView record in Pascal Francis$$Hfree_for_read</backlink><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/16332061$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Broene, Richard D</creatorcontrib><creatorcontrib>Brookhart, Maurice</creatorcontrib><creatorcontrib>Lamanna, William M</creatorcontrib><creatorcontrib>Volpe, Anthony F</creatorcontrib><title>Cobalt-Catalyzed Dimerization of α-Olefins to Give Linear α-Olefin Products</title><title>Journal of the American Chemical Society</title><addtitle>J. Am. Chem. Soc</addtitle><description>[Cp*P(OMe)3CoCH2CH3]+ [BarF]-, generated by the addition of HBArF to Cp*P(OMe)3Co(ethene), catalyzes the oligomerization of 1-hexene to give dimers and trimers. When a deficit of the acid is used, linear α-olefin dimers are produced at the expense of trimeric products: e.g., 1-butene, 1-hexene, and 1-octene give 1-octene, 1-dodecene, and 1-hexadecene, respectively.</description><subject>Chemistry</subject><subject>Exact sciences and technology</subject><subject>Kinetics and mechanisms</subject><subject>Organic chemistry</subject><subject>Reactivity and mechanisms</subject><issn>0002-7863</issn><issn>1520-5126</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2005</creationdate><recordtype>article</recordtype><recordid>eNpt0M9OGzEQBnALUUEaOPQFqr20Ug9bPN74T45laQIoCCTC2Rq8s5LDZg32bgW8VV-kz9RFiciF08ianz55Psa-AP8JXMDJCrlUSsp2j41ACp5LEGqfjTjnItdGFYfsc0qr4TkRBg7YIaiiEFzBiF2V4R6bLi-xw-bllarszK8p-lfsfGizUGf__ubXDdW-TVkXsrn_Q9nCt4Rxt8luYqh616Uj9qnGJtHxdo7Z3ez3sjzPF9fzi_LXIsfCQJcbzgFBOa5ICu2g4KiBgxFaTqQxTmuBwAmVIIU0JRRTM5W1kVQZhRUUY_Z9k_sYw1NPqbNrnxw1DbYU-mSVMWoC5g3-2EAXQ0qRavsY_RrjiwVu37qz790N9us2tL9fU7WT27IG8G0LMDls6oit82nndKGHU_Tg8o3zqaPn9z3GB6sGI-3y5tbOTmeT08tlaW93ueiSXYU-tkN3H3zwP3KykNY</recordid><startdate>20051214</startdate><enddate>20051214</enddate><creator>Broene, Richard D</creator><creator>Brookhart, Maurice</creator><creator>Lamanna, William M</creator><creator>Volpe, Anthony F</creator><general>American Chemical Society</general><scope>BSCLL</scope><scope>IQODW</scope><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7X8</scope></search><sort><creationdate>20051214</creationdate><title>Cobalt-Catalyzed Dimerization of α-Olefins to Give Linear α-Olefin Products</title><author>Broene, Richard D ; Brookhart, Maurice ; Lamanna, William M ; Volpe, Anthony F</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-a381t-8001a16c06e527c130a710182754588c772a10ea62e6ae9ea29895f85ed86ad13</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2005</creationdate><topic>Chemistry</topic><topic>Exact sciences and technology</topic><topic>Kinetics and mechanisms</topic><topic>Organic chemistry</topic><topic>Reactivity and mechanisms</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Broene, Richard D</creatorcontrib><creatorcontrib>Brookhart, Maurice</creatorcontrib><creatorcontrib>Lamanna, William M</creatorcontrib><creatorcontrib>Volpe, Anthony F</creatorcontrib><collection>Istex</collection><collection>Pascal-Francis</collection><collection>PubMed</collection><collection>CrossRef</collection><collection>MEDLINE - Academic</collection><jtitle>Journal of the American Chemical Society</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Broene, Richard D</au><au>Brookhart, Maurice</au><au>Lamanna, William M</au><au>Volpe, Anthony F</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Cobalt-Catalyzed Dimerization of α-Olefins to Give Linear α-Olefin Products</atitle><jtitle>Journal of the American Chemical Society</jtitle><addtitle>J. Am. Chem. Soc</addtitle><date>2005-12-14</date><risdate>2005</risdate><volume>127</volume><issue>49</issue><spage>17194</spage><epage>17195</epage><pages>17194-17195</pages><issn>0002-7863</issn><eissn>1520-5126</eissn><coden>JACSAT</coden><abstract>[Cp*P(OMe)3CoCH2CH3]+ [BarF]-, generated by the addition of HBArF to Cp*P(OMe)3Co(ethene), catalyzes the oligomerization of 1-hexene to give dimers and trimers. When a deficit of the acid is used, linear α-olefin dimers are produced at the expense of trimeric products: e.g., 1-butene, 1-hexene, and 1-octene give 1-octene, 1-dodecene, and 1-hexadecene, respectively.</abstract><cop>Washington, DC</cop><pub>American Chemical Society</pub><pmid>16332061</pmid><doi>10.1021/ja056655n</doi><tpages>2</tpages></addata></record> |
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| subjects | Chemistry Exact sciences and technology Kinetics and mechanisms Organic chemistry Reactivity and mechanisms |
| title | Cobalt-Catalyzed Dimerization of α-Olefins to Give Linear α-Olefin Products |
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